2(a) Specimen preparation

Three samples were selected from the Camp Century basal ice core for these tests, a “dark” sample (type 1 from 1375 m depth), an “intermediate” (or “medium”) sample (type 2 from 1 377 m) and a “clear” sample (type 3 from 1 379 m). The sample classification is based on visual observations of transmitted white light through the ice core using a light table (Reference Herron and LangwayHerron [S L] and Langway 1979). Each sample was more than 30 cm long and was cut into several specimens for microscopic observations (M) and simple shear tests (S). Samples were rough-cut with a bandsaw and the surface finished with a microtome to about 1 × 3 × 10 cm (for M) and (21.4 ± 0.05) × (22.4 ± 0.2) × (31.4 ± 0.4) mm (for S). Vertical and horizontal specimens (M) were prepared for observations of microstructure. Specimens for simple shear tests (S) were prepared so as to have the applied shear stress plane parallel to the horizontal plane of each ice-core sample. An additional specimen of type 2 was prepared so that the applied shear stress plane was inclined 45° from the horizontal plane so that the fabric enhancement factor could be examined.

2(b) Optical microscopic observation

Grain size was measured by the intercept method (Reference Herron and LangwayHerron [S L] and others 1982) under an optical microscope. Internal microstructure was observed and photographed for gas, liquid and solid inclusions. Evaporation pits were formed on the specimen surface by the formvar method (Reference HiguchiHiguchi 1958, Reference MatsudaMatsuda 1979) to determine the crystal orientations.

2(c) Simple shear tests

The simple shear creep testing apparatus was specially designed and constructed for this study. It was also used for the mechanical tests made on the fresh ice-core samples from the Dye 3 ice core very soon after recovery (Reference Shoji and LangwayShoji and Langway 1982[b]). The two side faces of the specimen were frozen onto brass plates so as to have a thickness of 31.4 mm. One of the plates was fixed to the frame of the apparatus whilst the other was allowed to slide vertically with a linear motion using vertical rods driven by a controlled weight. The vertical displacement of the sliding plate was recorded with a linear voltage differential transformer (LVDT) detector. The apparatus was contained in a temperature-control led insulated box in a laboratory cold room kept at −15°C. Temperature was measured with copper-constantan thermocouples and maintained at −13°C to conform with the measured value at the bottom of the Camp Century bore hole. The temperature fluctuation was within 0.2°C for each test run.

3(a) Optical microscope observations

The general characteristics of the types of basal ice relevant to the present study are given in Table I (Reference Herron and LangwayHerron [S L] and Langway 19791). Descriptions of the three samples tested are given in Table II.

Table I

General Characteristics of Basal Ice (Camp Century)

Table II

Microstructure of Basal Ice Samples (Camp Century)

Changes in physical properties of an ice core with time after core recovery were earlier reported using the pressure change with time of an air-bubble (Reference LangwayLangway 1958), This is essentially an ice deformation process centered around air bubbles and driven by a hydrostatic pressure difference between the gas in the air bubble and the ambient pressure (Reference Shoji and LangwayShoji and Langway 1983). The internal surfaces of air bubbles in basal ice samples (types 1, 2 and 3) were observed to be very smooth compared with those of bubbles in fresh ice core (Reference Shoji and LangwayShoji and Langway 1982[a]). This suggests that the air pressure in the gas bubbles may already be very close to ambient pressure and that the ice deformation around the air bubbles is no longer active. With the type 1 sample (dark ice), a significant decrease in color intensity was observed near the edges of the ice core. This is probably related to a process of diffusion from the center of the included impurities in the core outwards. Grain-size distribu-tion from the center of the cross-section of the core to the periphery also revealed a large increase in grain size from 0.5 mm at the center to 3 to 4 mm near the periphery. This change in grain size is observed in specimens from both horizontal and vertical sections (Fig.1). The triple junctions of grain boundaries are mostly decorated with small-sized debris particles as shown in Figure 2(a), which clearly identify the location of grain boundaries in three dimensions. Within large ice grains near the outer core surface, chain networks of air bubbles were often observed with a comparable network size (0.5 mm) to grain size near the center of the core (Fig.2(b)). Because of these alterations, specimens used for the shear tests were prepared from the non-recry stall ized central part of the original ice core. Microscopic observations also revealed that liquid veins and lenses formed at the triple junctions of grain boundaries and grain boundary planes, respectively (Fig.2(c)). The size of the liquid inclusions increased when the temperature of the sample was increased. Reference OguroOguro (1975) showed in his studies of the growth of single ice crystals using dilute aqueous solutions that pockets of solutions were formed when the concentration of impurity (NH₄F or nail in his studies) in the original solution exceeded 1 000 ppm. These liquid inclusions observed in type 1 samples (dark ice) were generally accompanied by debris particles or aggregates of particles in suspension.

Fig. 1

Grain-size distribution of type 1 sample, dark ice, with distance from ice core center. (a) horizontal section, (b) vertical section. Numerical values in parentheses are average grain sizes in mm.

Fig. 2

Microstructure of basal ice. Each vertical bar equals 0.2 mm. (a) triple junction of grain boundaries decorated with small debris particles, (b) air-bubble chain network observed within a large grain near the core surface, (c) liquid lenses (denoted by arrows) in a dark sample, (d) a transformation of a gas hydrate inclusion (left) into gas bubbles (right) under heat treatment. Arrows denote the same position at different times.

In the other two samples tested (clear ice, type 3 and 2 medium ice, type 2) a very small number of gas hydrate inclusions were observed which were similar to those found in the fresh ice core from Dye 3 (Reference Shoji and LangwayShoji and Langway 1982[a]). By using a heat treatment whereby the specimen is gradually melted under a microscope, the transformation of the gas hydrates into a large volume of individual gas bubbles, as shown in Figure 2(d), was observed. According to a phase diagram constructed by Reference MillerMiller (1969), an air hydrate inclusion in clathrate structure I is not stable under long-term ice-core storage (at about −30°C) and atmospheric pressure. This agrees with our observations that only a small number of gas hydrate inclusions remain for long after core recovery.

Results of ice-fabric analysis using the evaporation pit method are given in Table II (first quartile of c-axis verticality).

3(b) Simple shear tests

Each specimen was deformed more than 1.2% in shear-strain in order to obtain the necessary minimum creep rate (Reference Russell-Head and BuddRussell-Head and Budd 1979). The results show that these ice specimens have the highest shear strain-rate ever reported for polycrystalline ice under simple shear (Fig.3). Specimens of types 3 and 2 (clear and medium ices) have almost equal strain-rates, which are 40 to 100 times greater than those of laboratory prepared ice, and the type 1 specimens (dark ice) have about half the strain-rate of the other two types at the same stress level. We obtained a fabric enhancement factor of two for type 1 ice and four for type 2 and 3 ice using the diagram of Reference Russell-Head and BuddRussell-Head and Budd (1979). The strain-rate differences for the different types at the same stress level agrees quite well with those expected from the above fabric-factor diagram.

Fig. 3

Logarithmic plot of shear strain-rate versus shear stress. Simple shear stress was applied along the horizontal plane of the core. Sample “1377m, 45°” was tested with the applied simple shear stress inclined at 45° from the vertical axis of the core. Experimental results on randomly oriented artificial polycrystalline ice by Reference Barnes, Tabor and WalkerBarnes and others (1971) have been converted from uniaxial stress / strain-rate to shear stress/strain-rate using Reference NyeNye’s (1957) formula. All data points were experimentally obtained at a temperature of −13°C.

To investigate the hard-glide stress condition we tested another type 2 specimen with the stress direction 45° from the horizontal plane. This test resulted in a strain-rate one order of magnitude lower than that obtained by the previous easy glide orientation (Fig.3). This result also agreed with the change of fabric enhancement factor both calculated and measured by Reference LileLile (1978). Since the concentration of debris particles is less than 0.7% by weight in every sample tested (Table I), the dispersion-hardening effect of particles should be small or negligible as indicated by the experiments of Reference Hooke, Dahlin and KauperHooke and others (1972). X-ray studies show that microstructures of both impurity-doped crystals (Reference OguroOguro 1975) and relaxed ice-core samples (Reference ShojiShoji and Higashi 1978) have either mosaic patterns or sub-boundaries. Reference MugurumaMuguruma (1969) showed that the yield-stress of single ice-crystal specimens having sub-boundaries was as low as one quarter of those not having sub-boundaries. This softening is caused by the increase in mobile dislocation density. The softening effect created by HF doping is discussed in terms of dislocation mobility by Reference Jones and GlenJones and Glen (1969).

The values of enhancement factors obtained in this work and other published data enable us to calculate horizontal velocity profiles and subsequently to discuss depth-age relationships.

4(a) Strain-rate enhancement factor

Fabric enhancement factors vary from one (random plot) to four (strong single maximum plot) depending upon preferred stress direction as related to basal glide direction (Reference LileLile 1978, Reference Russell-Head and BuddRussell-Head and Budd 1979). In the case of hard glide deformation with a single fabric maximum, we estimate a fabric enhancement factor value of 0.1 based on our experimental data (Table III). For a highly relaxed ice core (considerable time after core recovery), we assigned a value of four to the ageing factor, based on experiments performed on fresh and relaxed ice cores (Reference Shoji and LangwayShoji and Langway 1982[b], Reference ShojiShoji unpublished) and experiments made under confined and unconfined stress conditions (Reference AzumaAzuma unpublished). For example, experimental results of the specimens taken from a depth of 300 m 4 to 8 a after core recovery from Byrd station showed a measured enhancement factor of six in uniaxial tension tests, although the estimated fabric enhancement factor is between 1 and 1.5 (Table III). This “softening” is taken into consideration as an ageing factor resulting from the mosaic/sub-boundary structure formed during the volume relaxation process after core recovery.

Table III

Estimation of Enhancement Factor

Table III gives a summary of unpublished experimental strain-rate data, together with measured total enhancement factors and estimated fabric/ageing enhancement factors. The remnant factor was defined as measured enhancement factor divided by product of fabric factor and ageing factor. A remnant factor greater than one is closely related to Wisconsin ice or basal silty ice, as is shown in Table III. Experiments showed that certain types of impurities such as HF and HCl soften ice by increasing the mobility of a dislocation and/or by increasing the density of mobile dislocations (Reference Jones and GlenJones and Glen 1969, Reference Nakamura, Jones, Whalley, Jones and GoldNakamura and Jones 1973). Chemical analyses made on polar ice cores reveal high Cl⁻ contents in Wisconsin ice (Reference Petit, Briat and RoyerPetit and others 1981 Reference Herron and LangwayHerron [M M] and Langway 1982). Our results also show that basal silty ice at Camp Century includes a high content of soluble impurities, although the HF content of ice cores has not been measured and the effect of other impurities such as SO₄ ²⁻ on the mechanical properties of ice is unknown. In this study we use the Cl⁻ content as an impurity factor indicator, although the measured concentration levels of Cl⁻ seems to be too low to have a significant effect on the strain-rate enhancement. The Cl⁻ concentration in both Camp Century and Dye 3 ice cores increases with distance from the bottom, and is extremely high in ice of the late-Wisconsin period (Reference Herron and LangwayHerron [M M] and Langway 1982). The highest Cl⁻ level is found at locations at, or just beneath, the Holocene/Wisconsin transition, located at 232 and 251 m from the bottom at Camp Century and Dye 3, respectively. Me assume an impurity enhancement factor of three for ice in which the Cl⁻ concentration is greater than half of that in late-Wisconsin ice. The impurity enhancement factor elsewhere is unity, except for silty ice at Camp Century which has an impurity factor of three.

4(b) Horizontal velocity profile

The estimated enhancement factors as a function of depth-interval for the Camp Century and Dye 3 ice cores are given in Table IV. Strain-rates for these depth intervals were calculated using an empirical flow law obtained by Reference Barnes, Tabor and WalkerBarnes and others (1971), and the enhancement factor mentioned above (assuming laminar flow). At Dye 3, the surface slope is 3.3 × 10⁻³ rad (Reference Overgaard and GundestrupOvergaard and Gundestrup 1982) and the temperature profile in the bore hole has been measured by Reference Gundestrup and JohnsenGundestrup and Johnsen (1982). Fabric studies on the Dye 3 ice core were made by Reference Herron and LangwayHerron [S L] and others (1982). The surface velocities calculated for Camp Century (3.4 m a⁻¹) and Dye 3 (13.5 m a⁻¹) agree quite well with the value of 3.3 m a⁻¹ measured at Camp Century and that of 12.3 m a⁻¹ at Dye 3 (N Gundestrup private communication). The velocity profiles obtained are shown in Figure 4. The results obtained from borehole tilting measurements at Camp Century (B L Hansen private communication) are shown in Figure 4(a) for the bottom 300 m. Hansen’s results show a higher strain-rate at shallow depths than our calculation, and a value of 5.5 m a⁻¹ for surface velocity.

Fig. 4

Smoothed horizontal velocity profiles calculated for Camp Century and Dye 3. Strain-rate calculations were made on each slab section at 10 to 100 m depth intervals (a greater spacing was used at shallow depths). Solid circles are calculated points at the depths for which the enhancement factor changes are deduced. Open circles shown in (a) were obtained from bore hole tilting measurements by B L Hansen (private communication).

Table IV

Estimated Enhancement Factors for Calculating a Velocity Profile

The horizontal velocity pattern calculated for Camp Century (Fig.4(a)) is quite similar to that calculated by Reference WeertmanWeertman (1968) except for two features:

• (1) the flow deformation of the ice sheet is highly concentrated within the Wisconsin depth interval, and

• (2) the shear strain-rate decreases with depth for the lowest 125 m. These same features are also shown in the calculated velocity pattern for Dye 3 (Fig. 4(b)).

4(c) Depth-age profile

When calculating a depth-age relationship for the Camp Century core using the velocity profile obtained in this work, and assuming a two-dimensional steady-state flow as used by Reference Dansgaard and JohnsenDansgaard and Johnsen (1969), we obtain comparable results to time scale 1. Our analysis shows that time scale 2 (Reference Dansgaard and ReehDansgaard and others 1982) is completely different from time scale 1 (calculated with ice-flow modeling of Reference Dansgaard and JohnsenDansgaard and Johnsen (1969)) for the bottom 250 m at Camp Century. The apparent discrepancy may result from variations in the horizontal velocity from those of the present day which occurred during the Wisconsin. The differences may be due to temperature, ice thickness, surface slope or enhancement factor differences, and accumulation rate was also probably different in the past. On the other hand, flow behavior can be estimated from time scale 2 itself. The time scale can be converted into an annual-layer thickness profile corresponding to the vertical velocity profile under a steady-state assumption. When a two-dimensional flow model is applied, the horizontal velocity pattern can be calculated from incompressibllity conditions. This is an inverse procedure of the one used by Reference Dansgaard and JohnsenDansgaard and Johnsen (1969) in which time scale 1 was calculated from the horizontal velocity pattern. It should be kept in mind, however, that additional hypotheses require additional assumptions. For these reasons, depth-age profiles for the Camp Century and Dye 3 ice cores have been plotted with log/1 in axes on Figure 5. The depth-age profile so plotted gives a straight line when the vertical strain-rate is constant with depth. Time scale 2 for both the Camp Century and Dye 3 ice cores are apparently linear for the bottom 250 m. Such a constant vertical strain-rate can be expected under a two-dimensional steady-state condition only when basal sliding is taking place. As discussed earlier, liquid lenses and veins were observed in type 1 (dark) ice in conjunction with debris particles which were incorporated from the base (Reference Herron and LangwayHerron [S L] and Langway 1979). This indicates it is not only the pressure-melting mechanism which can cause basal melting. Another possibility arises when three-dimensional flow occurs, as would be expected from the large amplitude of the basal irregularities compared with the ice thickness observed along the Dye 3 flow line (Reference Overgaard and GundestrupOvergaard and Gundestrup 1982). A constant vertical strain-rate might be attained if the transversal strain-rate compensates the longitudinal strain-rate as required by an incompressibility condition under a steady-state assumption.

Fig. 5

Depth-age profiles for Camp Century and Dye 3. Open and solid circles (time scale 2) are obtained from δ¹⁸O measurements. Solid line for Camp Century (time scale 1) was obtained by Reference Dansgaard and JohnsenDansgaard and Johnsen (1969). Broken line for Dye 3 (time scale 1) was obtained with Dansgaard and Johnsen’s model by Reference Dansgaard and ReehDansgaard and Reeh (1982).