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Dynamic drying transition via free-surface cusps

Published online by Cambridge University Press:  12 November 2018

Catherine Kamal
Affiliation:
School of Mathematics, University of Bristol, University Walk, Bristol BS8 1TW, UK
James E. Sprittles
Affiliation:
Mathematics Institute, University of Warwick, Coventry CV4 7AL, UK
Jacco H. Snoeijer
Affiliation:
Physics of Fluids Group, Faculty of Science and Technology, Mesa$+$ Institute, University of Twente, 7500 AE Enschede, The Netherlands
Jens Eggers*
Affiliation:
School of Mathematics, University of Bristol, University Walk, Bristol BS8 1TW, UK
*
†Email address for correspondence: Jens.Eggers@bristol.ac.uk

Abstract

We study air entrainment by a solid plate plunging into a viscous liquid, theoretically and numerically. At dimensionless speeds $Ca=U\unicode[STIX]{x1D702}/\unicode[STIX]{x1D6FE}$ of order unity, a near-cusp forms due to the presence of a moving contact line. The radius of curvature of the cusp’s tip scales with the slip length multiplied by an exponential of $-Ca$. The pressure from the air flow drawn inside the cusp leads to a bifurcation, at which air is entrained, i.e. there is ‘wetting failure’. We develop an analytical theory of the threshold to air entrainment, which predicts the critical capillary number to depend logarithmically on the viscosity ratio, with corrections coming from the slip in the gas phase.

Information

Type
JFM Papers
Creative Commons
Creative Common License - CCCreative Common License - BY
This is an Open Access article, distributed under the terms of the Creative Commons Attribution licence (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted re-use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright
© 2018 Cambridge University Press
Figure 0

Figure 1. A sketch of the transition to air entrainment produced by a plate descending vertically into a liquid bath. Below the transition (a), the interface meets the solid at a contact line, above which the solid is dry, and below which it is covered with liquid. Above the transition (b), a thin film of air has been entrained. (c) Shows an experiment example of a quasi-steady interface before and after the transition to air entrainment, taken from Vandre, Carvalho & Kumar (2013). At the lower edge of the entrained sheet, sawtooth-shaped instabilities are often observed.

Figure 1

Figure 2. Simulations and experimental data of $Ca_{cr}$ for different $M$. The experimental data are taken: from Vandre, Carvalho & Kumar (2014) for a glycerol–air experimental set-up with $\unicode[STIX]{x1D703}_{e}\approx 81^{\circ }$ and baths of different widths $H$ ($\unicode[STIX]{x03BC}\text{m}$); from Marchand et al. (2012) for a silicone oil–air set-up with $\unicode[STIX]{x1D703}_{e}\approx (51^{\circ },57^{\circ })$ for either (I) the measured speed at which rupture of the free interface is first seen or (II) the speed of the growth of the rewetting ridge; from Benkreira & Khan (2008) for a silicone oil–air set-up ($\unicode[STIX]{x1D703}_{e}\approx 60^{\circ }$); from Burley & Kennedy (1976); and from Blake & Shikhmurzaev (2002). The numerical data are from Sprittles (2017) and Vandre et al. (2014), with $\unicode[STIX]{x1D703}_{e}=90^{\circ }$ in both cases.

Figure 2

Figure 3. Bifurcation curves as obtained from FEM simulations for $\unicode[STIX]{x1D703}_{e}=\unicode[STIX]{x03C0}/2$ and different viscosity ratio $M$, compared to results of the GL approximation (A 1); the slip length is $\unicode[STIX]{x1D706}=10^{-5}$. The vertical lines represent the location of $Ca_{cr}$ for the FEM simulation (dotted) and the GL approximation (dashed). The upper branch is stable, the lower unstable. For small $M$, the GL approximation bifurcates at much larger values of $Ca$ than predicted by numerical simulation.

Figure 3

Figure 4. A sketch of a plate plunging vertically into a bath. On some outer scale (a), a near-cusp forms between the liquid interface and plate. This is the cusp region (I). Assuming the bath to be very wide compared to $\unicode[STIX]{x1D6E5}$ (the distance from the contact line to the bath), the interface eventually becomes very flat. This is represented by the bath region (III). On some inner scale, $R$, the cusp must round and make contact with the plate (b). This is known as the contact line region (II). The numbering reflects the order in which the zones are analysed.

Figure 4

Figure 5. The interface for $Ca=1.04$ and $M=0$ (solid line), $M=1.5\times 10^{-6}$ (dot-dashed line) and $M=10^{-5}$ (dashed line). On the macroscale, the interface approaches a $180^{\circ }$ contact angle, but bends on some inner scale towards $\unicode[STIX]{x1D703}_{e}=\unicode[STIX]{x03C0}/2$, as seen in the inset. On the macroscale there is little difference as $M$ increases; only on some intermediate scale about the contact line (shown in the inset) can the effect of a finite $M$ be seen.

Figure 5

Figure 6. (a) Sketch of the cusp solution for a $180^{\circ }$ contact angle. (b) Solutions of (2.9).

Figure 6

Figure 7. Plots of FEM profiles of the liquid interface (black curved line) at different $Ca$. The (red) solid straight lines are best fits to the intermediate region $h=ax^{q}$, where $q$ is defined by (2.10), and the (red) dashed straight lines are those to the cusp exponent $3/2$. The prefactor $a$ (in units of $l_{c}$) is $0.76$ and $0.49$, respectively. The best fits are made to approximate the shape of the free surface; the slip length is $\unicode[STIX]{x1D706}=10^{-4}$.

Figure 7

Figure 8. The prefactor $a$ in (2.3) as a function of $Ca$. The circles represent values of $a$ obtained by fitting (2.3) to numerical simulations as shown in figure 7. The solid line is an empirical fit $a=0.45+0.82\exp (-1.31Ca)$, suggesting that $a$ will rapidly approach a finite value as $Ca\rightarrow \infty$.

Figure 8

Figure 9. The composite solution (2.13) (red dashed line) fitted to a FEM simulation of the free surface (black solid line) for two different contact angles; $\unicode[STIX]{x1D706}=10^{-4}$. The fitting parameters are $R/\unicode[STIX]{x1D706}\approx 3.4\times 10^{-4}$ and $a=0.52$ (a), and $R/\unicode[STIX]{x1D706}=0.011$$a=0.66$ (b). The inset on the left shows that the composite solution (2.13) slightly underestimates the rate of increase of the interface near the crossover.

Figure 9

Figure 10. Plot of $R/\unicode[STIX]{x1D706}$ for $\unicode[STIX]{x1D703}_{e}=\unicode[STIX]{x03C0}/2$ and different slip lengths. The radius $R$ is found by fitting (2.13) to FEM simulations. All data collapse according to (2.18), with $C=4.29$.

Figure 10

Figure 11. Plot of $R/\unicode[STIX]{x1D706}$ for different $\unicode[STIX]{x1D703}_{e}$. The radius $R$ is found by fitting (2.13) to FEM simulations, just like for $\unicode[STIX]{x1D703}_{e}=90^{\circ }$. As $Ca$ increases, all curves eventually collapse onto a line with exponent $-2\unicode[STIX]{x03C0}$. The value of $C$ in (2.18) is $C=3.22$ for $\unicode[STIX]{x1D703}_{e}=80^{\circ }$, $C=4.29$ for $\unicode[STIX]{x1D703}_{e}=90^{\circ }$ and $C=146$ for $\unicode[STIX]{x1D703}_{e}=100^{\circ }$.

Figure 11

Figure 12. FEM simulations of the interface about the bath for $Ca=0.75$, 1.04 and 1.49 (bottom to top) for $H_{b}=10^{3}$ (black lines). The short (red) line in the main panel represents the power law $h\sim (\unicode[STIX]{x1D6E5}-x)^{-1}$. In the inset we show the coefficient of proportionality $a_{1}$ as found by fitting FEM simulations to $h=a_{1}(\unicode[STIX]{x1D6E5}-x)^{-1}$ and compare to the theoretical prediction (2.22) (red line).

Figure 12

Figure 13. Bifurcation curve obtained from theory, using the base flow obtained from numerical simulation at $M=0$ for $Ca=0.65$ and $Ca=1.04$ (solid black line), compared to full FEM simulations (red line). The contact angle is $\unicode[STIX]{x1D703}_{e}=\unicode[STIX]{x03C0}/2$ and slip lengths are $\unicode[STIX]{x1D706}_{l}=\unicode[STIX]{x1D706}_{g}=10^{-4}$. Vertical dashed lines mark the critical values $M_{cr}$.

Figure 13

Figure 14. The critical capillary number $Ca_{cr}$ as a function of $M$ according to FEM data (red squares) and theory (blue circles), for $\unicode[STIX]{x1D706}=\unicode[STIX]{x1D706}_{g}=10^{-4}$ and $\unicode[STIX]{x1D703}_{e}=\unicode[STIX]{x03C0}/2$. The solid line corresponds to the analytical prediction according to (3.14), and the dashed line is the analytical prediction including slip between gas and the liquid; the vertical dotted line denotes the theoretical limit (3.19) below which no bifurcation occurs.