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Turbulent flows over superhydrophobic surfaces: flow-induced capillary waves, and robustness of air–water interfaces

Published online by Cambridge University Press:  27 November 2017

Jongmin Seo
Affiliation:
Center for Turbulence Research, Stanford University, Stanford, CA 94305, USA
Ricardo García-Mayoral
Affiliation:
Center for Turbulence Research, Stanford University, Stanford, CA 94305, USA Department of Engineering, University of Cambridge, Cambridge CB2 1PZ, UK
Ali Mani*
Affiliation:
Center for Turbulence Research, Stanford University, Stanford, CA 94305, USA
*
†Email address for correspondence: alimani@stanford.edu

Abstract

Superhydrophobic surfaces can retain gas pockets within their microscale textures when submerged in water. This property reduces direct contact between water and solid surfaces and presents opportunities for improving hydrodynamic performance by decreasing viscous drag. In most realistic applications, however, the flow regime is turbulent and retaining the gas pockets is a challenge. In order to overcome this challenge, it is crucial to develop an understanding of physical mechanisms that can lead to the failure of superhydrophobic surfaces in retaining gas pockets when the overlying liquid flow is turbulent. We present a study of the onset of failure in gas retention by analysing direct numerical simulations (DNS) of turbulent flows over superhydrophobic surfaces coupled with the deformation of air–water interfaces that hold the gas pockets. The superhydrophobic surfaces are modelled as periodic textures with patterned slip and no-slip boundary conditions on the overlying water flow. The liquid–gas interface is modelled via a linearized Young–Laplace equation, which is solved coupled with the overlying turbulent flow. A wide range of texture sizes and interfacial Weber numbers are considered in this study. Our analysis identifies flow-induced upstream-travelling capillary waves that are coherent in the spanwise direction as one mechanism for failure in retention of gas pockets. To confirm physical understanding of these waves, a semianalytical inviscid linear analysis is developed; the wave speeds obtained from the space–time correlations in the DNS data were found to match with the predictions of the semianalytical model. The magnitude of the pressure fluctuations due to these waves was found to increase with decreasing surface tension, and increase with a much stronger dependence on the slip velocity, when all numbers are reported in wall units. Based on a fitted scaling, a threshold criterion for the failure of superhydrophobic surfaces is developed that is based on estimates of the onset condition required for the motion of contact lines. The second contribution of this work is the development of boundary maps that identify stable and unstable zones in a parameter space consisting of working parameter and design parameters including texture size and material contact angle. We provide a brief description of previously identified failure modes of superhydrophobic surfaces, namely the stagnation pressure and shear-driven drainage mechanisms. In an overlay map, the stable and unstable zones due to each mechanism are presented. For various input conditions, we provide scaling laws that identify the most critical mechanism limiting the stability of gas retention by superhydrophobic surfaces.

Information

Type
JFM Papers
Copyright
© 2017 Cambridge University Press 
Figure 0

Figure 1. Schematic representation of a channel flow with superhydrophobic surfaces on both top and bottom walls: (a) isotropic posts (b) streamwise ridges.

Figure 1

Figure 2. (a) Schematic of patterned slip and no-slip boundary conditions at superhydrophobic surfaces with deformable interfaces. The interface location is defined as $\unicode[STIX]{x1D702}$, which is the vertical distance from the wall plane. (b) Gas–liquid interface on solid posts. For both figures, the baseline wall location $(y=0)$ is denoted by dashed lines.

Figure 2

Table 1. Simulation parameters. $L^{+}$ is the pattern spacing, $We_{L}$ is Weber number based on $L$ and $u_{\unicode[STIX]{x1D70F}}$, and $Re_{\unicode[STIX]{x1D70F}}$ is the friction Reynolds number. Domain size in viscous units is $D_{x}^{+}$ and $D_{z}^{+}$ for the streamwise and spanwise directions, respectively. The number of grid points is $N_{x}$, $N_{z}$, and $N_{y}$, for streamwise, spanwise, and wall-normal directions respectively. The grid size is given by the computational domain size and number of grid points. $DR$ is the drag reduction obtained by $DR=(C_{f,smooth}-C_{f,SHS})/C_{f,smooth}$, where $SHS$ stands for superhydrophobic surface.

Figure 3

Figure 3. Comparison of statistics for post geometries at $L^{+}\approx 155$, $Re_{\unicode[STIX]{x1D70F}}\approx 200$, and $We_{L}=2\times 10^{-3}$. (a) Mean streamwise velocity profile; (b) velocity r.m.s. fluctuations; (c) pressure r.m.s. fluctuations. –○–, posts with $\unicode[STIX]{x0394}x^{+}=6.4,\unicode[STIX]{x0394}z^{+}=3.2$ –♦–, posts with $\unicode[STIX]{x0394}x^{+}=3.2,\unicode[STIX]{x0394}z^{+}=1.6$.

Figure 4

Figure 4. Comparison of statistics at $L^{+}\approx 155$, $w^{+}\approx 52$ at $Re_{\unicode[STIX]{x1D70F}}\approx 200$. (a,d) Mean streamwise velocity profile; (b,e) three components of velocity root-mean-square (r.m.s.) fluctuations; (c,f) pressure r.m.s. fluctuations. –●–: P155, posts with $We_{L}=0$ (Seo et al.2015); –○–: P155W2, posts with $We_{L}=2\times 10^{-3}$; –▹–: R155, streamwise ridges with $We_{L}=0$ (Seo et al.2015); –▸–: R155W2, streamwise ridges with $We_{L}=2\times 10^{-3}$; – – – –: smooth walls, $Re_{\unicode[STIX]{x1D70F}}\approx 200$ (Seo et al.2015).

Figure 5

Figure 5. Comparison of instantaneous interface heights, $\unicode[STIX]{x1D702}^{+}=\unicode[STIX]{x1D702}/\unicode[STIX]{x1D6FF}_{\unicode[STIX]{x1D708}}$, for two different superhydrophobic textures for $Re_{\unicode[STIX]{x1D70F}}\approx 200$, $L^{+}\approx 155$ and $We_{L}=2\times 10^{-3}$. (a) Posts, P155W2, (b) streamwise ridges, R155W2. The dashed lines are the baseline wall location $y^{+}=0$. The axis for $\unicode[STIX]{x1D702}^{+}$ is 300 times magnified for visualization purposes.

Figure 6

Figure 6. Comparison of instantaneous pressure contours, $p^{+}=p/(\unicode[STIX]{x1D70C}u_{\unicode[STIX]{x1D70F}}^{2})$, at $y^{+}=0$, for cases at $Re_{\unicode[STIX]{x1D70F}}\approx 200$, and $L^{+}\approx 155$. (a) P155, $We_{L}=0$, (Seo et al.2015) (b) P155W2, $We_{L}=2\times 10^{-3}$, (c) R155, $We_{L}=0$, (Seo et al.2015) (d) R155W2, $We_{L}=2\times 10^{-3}$. From blue to yellow, the fluctuations range between $-10$ and $10$ wall units. Snapshots from cases with finite surface tension are taken at the same instance in which the interface deformations in figure 5 are taken. The main flow direction is left to right.

Figure 7

Figure 7. Successive instantaneous snapshots of wall pressure fluctuations, $p^{+}$, in time for P155W2 with $Re_{\unicode[STIX]{x1D70F}}\approx 200$, $L^{+}\approx 155$ and $We_{L}=2\times 10^{-3}$. From (a) to (f), $t=t_{0}+[0:2:10]~\unicode[STIX]{x0394}t$, where $\unicode[STIX]{x0394}t=\unicode[STIX]{x1D6FF}_{\unicode[STIX]{x1D708}}/u_{\unicode[STIX]{x1D70F}}$. The main flow direction is left to right. From blue to yellow, the fluctuations range between $-10$ and 10 wall units.

Figure 8

Figure 8. Comparison of space–time correlations of dynamic pressure signals, $p^{+}$ at $y^{+}=0$, for cases with $Re_{\unicode[STIX]{x1D70F}}\approx 200$ and $L^{+}\approx 155$. From black to white, the correlation ranges between $-1$ and 1. (a) $We_{L}=2\times 10^{-3}$, (b) $We_{L}=0$. The solid lines represent the mean advection of the turbulent eddies, $U_{c_{1}}^{+}\approx 24$. The dashed line represents the phase velocity of the upstream-travelling, spanwise-coherent structures, $U_{c_{2}}^{+}\approx -38$.

Figure 9

Figure 9. Comparison of statistics for posts geometries with $L^{+}\approx 155$, $We_{L}=2\times 10^{-3}$ at $Re_{\unicode[STIX]{x1D70F}}\approx 200$ and $Re_{\unicode[STIX]{x1D70F}}\approx 400$. (a) Mean streamwise velocity profile minus the slip velocity; (b) velocity r.m.s. fluctuations; (c) pressure r.m.s. fluctuations. –●–, P155W2, posts at $Re_{\unicode[STIX]{x1D70F}}\approx 200$; – – – –, smooth walls, $Re_{\unicode[STIX]{x1D70F}}\approx 200$; –○–, P155W2$_{Re}$, posts at $Re_{\unicode[STIX]{x1D70F}}\approx 400$; ——, smooth walls, $Re_{\unicode[STIX]{x1D70F}}\approx 400$.

Figure 10

Figure 10. (a) Instantaneous pressure contours, $p^{+}$, at $y^{+}=0$ for the P155W2$_{Re}$ case with $L^{+}\approx 155$, $We_{L}=2\times 10^{-3}$ at $Re_{\unicode[STIX]{x1D70F}}\approx 400$. Inset figure in the bottom left quarter of figure is an overlay of instantaneous pressure contours at $Re_{\unicode[STIX]{x1D70F}}\approx 200$. From blue to yellow, the fluctuations range between $-10$ and 10 wall units. (b) Space–time correlations of dynamic pressure signals at $Re_{\unicode[STIX]{x1D70F}}\approx 400$. ——: $U_{c_{1}}^{+}\approx 24$; – – – –: $U_{c_{2}}^{+}\approx -38$. From black to white, the correlation ranges between $-1$ and 1.

Figure 11

Figure 11. Instantaneous wall pressure, $p^{+}$, contours for cases with $Re_{\unicode[STIX]{x1D70F}}\approx 200$ and $L^{+}\approx 77$. (a) $We_{L}=10^{-3}$, (b) $We_{L}=2\times 10^{-3}$, (c) $We_{L}=4\times 10^{-3}$.

Figure 12

Figure 12. Instantaneous interface deformation, $\unicode[STIX]{x1D702}^{+}$, for cases with $Re_{\unicode[STIX]{x1D70F}}\approx 200$ and $L^{+}\approx 77$. (a) $We_{L}=10^{-3}$, (b) $We_{L}=2\times 10^{-3}$, (c) $We_{L}=4\times 10^{-3}$. The dashed lines represent the baseline wall location $y^{+}=0$. Snapshots are taken at the same instance in which the pressure snapshots in figure 11 are taken. The dashed lines are the baseline wall location $y^{+}=0$. The axis for $\unicode[STIX]{x1D702}^{+}$ is 300 times magnified for visualization purposes.

Figure 13

Figure 13. Comparison of space–time correlations of dynamic wall pressure signals, $p^{+}$, for cases with $Re_{\unicode[STIX]{x1D70F}}\approx 200$ and $L^{+}\approx 77$. (a) $We_{L}=10^{-3}$, – – – –: $U_{c_{2}}^{+}\approx -23$; (b) $We_{L}=2\times 10^{-3}$, – – – –: $U_{c_{2}}^{+}\approx -42$; (c) $We_{L}=4\times 10^{-3}$, – – – –: $U_{c_{2}}^{+}\approx -78$. ——: $U_{c_{1}}^{+}\approx 21$ for all cases.

Figure 14

Figure 14. Instantaneous wall pressure contours, $p^{+}$ with (a) $L^{+}\approx 26$, (b) $L^{+}\approx 38$, (c) $L^{+}\approx 77$ at $We_{L}=4\times 10^{-3}$ and $Re_{\unicode[STIX]{x1D70F}}\approx 200$. From blue to yellow, the fluctuations range between $-10$ and 10 wall units.

Figure 15

Figure 15. Statistics of interfacial quantities scaled in viscous units versus $We_{L}$. (a) Wavelength of upstream-travelling wave in the streamwise direction, $\unicode[STIX]{x1D706}_{x}^{+}$; (b) time period of the upstream-travelling wave, $T^{+}$; (c) convection velocity of the upstream-travelling wave, $U_{c}^{+}$. ♦: $L^{+}\approx 26$, ▪: $L^{+}\approx 38$, ▴: $L^{+}\approx 77$, ●: $L^{+}\approx 155$. Symbols are computed by averaging at least four uncorrelated signals, and error bars plotted on top of the symbols.

Figure 16

Figure 16. Statistics of interfacial quantities scaled with $L$ and $U_{s}$ versus $We_{s}$. (a) wavelength of the upstream-travelling wave scaled by the texture size, $\unicode[STIX]{x1D706}^{\ast }=\unicode[STIX]{x1D706}_{x}/L$; (b) time frequency of the upstream-travelling wave, $T^{\ast }=TU_{s}/L$; (c) convection velocity of the upstream-travelling wave scaled by the slip velocity, $U_{c}^{\ast }=U_{c}/U_{s}$. ♦: $L^{+}\approx 26$, ▪: $L^{+}\approx 38$, ▴: $L^{+}\approx 77$, ●: $L^{+}\approx 155$.

Figure 17

Figure 17. Successive instantaneous realizations of the pressure at $y=0$ for the model problem with $\unicode[STIX]{x1D706}_{x}=2L$ and $\unicode[STIX]{x1D714}\approx 6.1U/L$. From (a) to (f), $t=t_{0}+2\unicode[STIX]{x03C0}/\unicode[STIX]{x1D714}\times [0:0.2:1]$.

Figure 18

Table 2. Solutions to the linearized, inviscid flow over superhydrophobic posts. From each DNS, $U$ for the model is estimated as the slip velocity, $U=U_{s}$ to obtain a Weber number $We_{s}=We_{L}{U_{s}^{+}}^{2}$. From all the possible frequencies $\unicode[STIX]{x1D714}^{\ast }=\unicode[STIX]{x1D714}L/U$ for which (5.6) is satisfied, only the one with wavelength $\unicode[STIX]{x1D706}^{\ast }=\unicode[STIX]{x1D706}_{x}/L$ close to that observed in the DNS is shown. $U_{c}^{+}$ is the convection velocity of the corresponding solution, for which the model $U_{c,model}^{+}$ is to be compared with that measured from the DNS, $U_{c,DNS}^{+}$.

Figure 19

Figure 18. Dimensionless time frequency solutions, $\unicode[STIX]{x1D714}^{\ast }$, from the semianalytical model. (a) $\unicode[STIX]{x1D714}^{\ast }$ versus $\unicode[STIX]{x1D706}^{\ast }$ with an arrow with increasing $We_{s}=0.1{-}2.0$ with successive interval 0.1. (b) $\unicode[STIX]{x1D714}^{\ast }\sqrt{\unicode[STIX]{x1D706}^{\ast }}$ versus $We_{s}$ with an arrow with increasing $\unicode[STIX]{x1D706}^{\ast }=2^{2},2^{3},2^{4}$.

Figure 20

Figure 19. Decomposition of wall pressure fluctuations for $L^{+}\approx 155$ and $We_{L}=4\times 10^{-3}$. (a) total r.m.s. pressure fluctuation, $p_{rms}^{\prime +}$, (b) r.m.s. stagnation pressure fluctuation, $\tilde{p}_{rms}^{+}$, (c) r.m.s. capillary pressure $p_{c,rms}^{\prime \prime +}$, (d) r.m.s. turbulence pressure, $p_{t,rms}^{\prime \prime +}$.

Figure 21

Figure 20. Statistics of fluctuations of interface deformation and capillary pressure versus $We_{L}$. (a) r.m.s. interface deformation in wall units, $\unicode[STIX]{x1D702}_{rms}^{+}$, (b) r.m.s. capillary pressure $p_{c}^{\prime \prime +}$ in wall units, ▾: $L^{+}\approx 13$, ♦: $L^{+}\approx 26$, ▪: $L^{+}\approx 38$, ▴: $L^{+}\approx 77$, ●: $L^{+}\approx 155$.

Figure 22

Figure 21. Statistics of fluctuations of dimensionless r.m.s. capillary pressure, $p_{c}^{\prime \prime +}$, versus $We_{s}$. ▾: $L^{+}\approx 13$, ♦: $L^{+}\approx 26$, ▪: $L^{+}\approx 38$, ▴: $L^{+}\approx 77$, ●: $L^{+}\approx 155$. – – – –: $p_{c,rms}^{\prime \prime +}\approx 0.06We_{s}^{0.57}{U_{s}^{+}}^{2.8}{L^{+}}^{-0.74}$.

Figure 23

Figure 22. Scaling of interfacial quantities scaled in $L$ and $U_{s}$ versus $We_{s}$. (a) Wavelength of capillary wave in streamwise direction, $\unicode[STIX]{x1D706}^{\ast }$; (b) convection velocity of capillary wave, $U_{c}^{\ast }$. ♦: $L^{+}\approx 26$, ▪: $L^{+}\approx 38$, ▴: $L^{+}\approx 77$, ●: $L^{+}\approx 155$. – – – –: $\unicode[STIX]{x1D706}^{\ast }\approx 1.9{We_{s}}^{-0.5}$, — ⋅ —: $U_{c}^{\ast }\approx 1.2{We_{s}}^{-1}$.

Figure 24

Figure 23. (a) Scalings of wall pressure fluctuations, $p_{0,rms}^{+}$. $\tilde{p}_{s}^{+}$ is wall pressure fluctuation by stagnation pressure, $\tilde{p}_{s,rms}^{+}\approx 0.28U_{s}^{+}+1.26$ (Seo et al.2015). $p_{c}^{\prime \prime +}$ is wall pressure fluctuation by capillary pressure, $p_{c,rms}^{\prime \prime +}\approx 0.06{We^{+}}^{0.57}{U_{s}^{+}}^{3.9}{L^{+}}^{-0.17}$. (b) Schematic of example calculation showing interface deformation due to an overlying pressure field. When the slope of the interface at the edge of the post form an angle, $\unicode[STIX]{x1D703}_{L}$, larger than the advancing contact angle, the interface starts to move.

Figure 25

Figure 24. Design map for the stable drag reduction of superhydrophobic surfaces in turbulent flows. $L_{c}^{+}$ is the maximum allowable texture size for stable drag reduction. $We^{+}=\unicode[STIX]{x1D707}u_{\unicode[STIX]{x1D70F}}/\unicode[STIX]{x1D70E}$ is Weber number based on inner scaling. The grey area is the unstable region and the white area is the stable region. (a) Shows the stability criteria imposed by stagnation pressure and capillary pressure. The dashed-dot lines are error bounds of the estimation of stability boundary for capillary pressure. (b) Shows the effect of texture randomness on the total stability region. Dashed lines are stability criteria imposed by stagnation pressure and capillary pressure for aligned posts. (c) Shows the effect of turbulence pressure on the total stability region. Dashed line is the solid curve in panel (b). Three different lines are plotted from different confidence intervals for pressure variation: 95 % (c), 99 % (b), 99.99 % (a). The area below the dotted lines indicates the region where $DR$ is less than 1 %. All analyses use the advancing contact angle $\unicode[STIX]{x1D703}_{adv}=120^{\circ }$ with the solid fraction of $\unicode[STIX]{x1D719}_{s}=0.11$.

Figure 26

Figure 25. Total design map for the stable drag reduction of superhydrophobic surfaces in turbulent flows. $L_{c}^{+}$ is the maximum allowable texture size for stable drag reduction. $We^{+}=\unicode[STIX]{x1D707}u_{\unicode[STIX]{x1D70F}}/\unicode[STIX]{x1D70E}$ is Weber number based on inner scaling. Arrows indicate the variability of stability of gas pockets when increasing velocity fixing fluid and design parameters. The upper solid line uses $\unicode[STIX]{x1D703}_{adv}=120^{\circ }$, and the bottom solid line uses $\unicode[STIX]{x1D703}_{adv}=100^{\circ }$ in the analysis of the failure mechanisms. Dashed lines are the failure boundaries imposed by stagnation and capillary pressure fluctuations. The dotted line is a boundary below which the drag reduction is expected to be under 1 %. The boundary map is obtained for the solid fraction $\unicode[STIX]{x1D719}_{s}=0.11$ and 95 % confidence level for the effect of turbulence pressure.

Figure 27

Figure 26. Schematic representations of barriers to prevent the shear-driven drainage and stability criteria. $L$ is pattern period of post arrays, $L_{\infty }$ is period of barriers, and $N_{p}$ is the number of periods in a barrier, $N_{p}=L_{\infty }/L$. (a) Posts enclosed by barriers with $N_{p}=4$, (b) posts enclosed by barriers with $N_{p}=2$. (c) Change of stability criteria according to the relative importance of shear-driven failure mechanism to stagnation pressure failure mechanism. $\unicode[STIX]{x1D707}_{a}$ is viscosity of air, $\unicode[STIX]{x1D707}_{w}$ is viscosity of water, $L^{+}$ is pattern period in wall units. Dashed lines are predicted stability boundaries imposed by shear-driven failure depending on the ratio between stagnation and shear-driven pressure.

Figure 28

Figure 27. Representation of DNS parameters on the design map. ▾: $L^{+}\approx 13$, ♦: $L^{+}\approx 26$, ▪: $L^{+}\approx 38$, ▴: $L^{+}\approx 77$, ●: $L^{+}\approx 155$.

Figure 29

Figure 28. Streamwise velocity (a–c) and pressure (d–f) snapshots in $z/\unicode[STIX]{x1D6FF}=0$ at time $tU/\unicode[STIX]{x1D6FF}=0,0.02,0.04$, respectively. Blue and red solid lines are from numerical simulations, and black dashed lines are analytical solutions (C 9), (C 11). Blue line is for negative values, and red line is for positive values.

Figure 30

Figure 29. Time evolution of interface location normalized by its initial magnitude. (a) Oscillation–diffusion–advection of gas–liquid interface. From blue to red, the lines are from time snapshots in $tU/\unicode[STIX]{x1D6FF}=0{-}1.5$ with a time interval 0.1. (b) A trace of a peak point in the initial condition. The solid magenta line is the numerical solution. For both plots, dashed-dot lines are analytical solutions.

Seo et al. supplementary movie 1

Instantaneous pressure field at y=0, for Re_Tau=197.5, L+=155, and We_L=0.002.

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Seo et al. supplementary movie 2

Instantaneous pressure field at y=0, for Re_Tau=197.5, L+=38, and We_L=0.004.

Download Seo et al. supplementary movie 2(Video)
Video 3.3 MB