1. Introduction
In recent years, a lot of interest has been shown in the field of pair-ion (PI) plasmas, which are composed of two ion components with equal mass and opposite charges. The PI plasma plays a significant role in plasma physics due to numerous astrophysical environments such as the pulsar magnetosphere, active galactic nuclei, neutron stars etc., where intense energies create electrons and positrons through pair production and annihilation. The PI plasma is expected to be used for the synthesis of dimers directly from carbon allotropes, as well as for nanotechnology (Deng, Clegg & Echt Reference Deng, Clegg and Echt2003; Shukla & Stenflo Reference Shukla and Stenflo2005). The physics of the PI plasma became more interesting when its application extended to the terrestrial laboratory. Oohara and Hatakeyama (Oohara & Hatakeyama Reference Oohara and Hatakeyama2003; Oohara, Date & Hatakeyama Reference Oohara, Date and Hatakeyama2005) developed a novel method for the generation of a PI plasma by impact ionization of a gas of fullerene
$(\text{C}_{60})$
carbon. By magnetic filtering of the plasma, the electrons and ions are removed and an almost PI plasma, consisting of singly charged
$\text{C}_{60}^{+}$
and
$\text{C}_{60}^{-}$
ions, was created. This gave rise to the unique possibility of investigating the collective behaviour of a PI plasma experimentally under controlled conditions. In an extended series of experiments, Nakamura et al. studied soliton propagation in a positive ion–negative ion plasma (Nakamura & Tsukabayashi Reference Nakamura and Tsukabayashi1984; Nakamura et al.
Reference Nakamura, Tsukabayashi, Ludwig and Ferreira1985). Cooney et al. (Reference Cooney, Gavin, Tao and Lonngren1991) experimentally observed a two-dimensional soliton in a PI plasma.
In the last few years, a lot of research work has already been done to explore the linear as well as nonlinear properties of PI plasmas so as to understand astrophysical plasmas, such as magnetospheric, ionospheric, solar wind pair plasmas, etc. (Luque et al. Reference Luque, Schamel, Eliasson and Shukla2005; Schamel & Luque Reference Schamel and Luque2005; Vranjes & Poedts Reference Vranjes and Poedts2005; Mahajan, Shatashvili & Berezhiani Reference Mahajan, Shatashvili and Berezhiani2009; Kourakis & Saini Reference Kourakis and Saini2010; Malekolkalami & Mohammadi Reference Malekolkalami and Mohammadi2012). Vladimirov et al. (Reference Vladimirov, Ostrikov, Yu and Morfill2003) studied ion acoustic waves (IAWs) in a low-temperature plasma containing dust particles and negative ions. Mahajan & Shatashvili (Reference Mahajan and Shatashvili2008) investigated the nonlinear propagation of high-intensity electromagnetic waves in a PI plasma. Vranjes et al. (Reference Vranjes, Petrovic, Pandey and Poedts2008) reported that electrons might be added to the PI plasma to study their effects on the plasma stability. Tribeche et al. (Reference Tribeche, Gougam, Boubakour and Zerguini2007) studied electrostatic solitary structures in a charge-varying PI dusty plasma. Recently, Arshad & Mahmood (Reference Arshad and Mahmood2010) investigated electrostatic ion waves in a non-Maxwellian PI plasma. Abdelsalam (Reference Abdelsalam2010) studied the nonlinear properties of the dust–ion acoustic waves in a collisionless PI dense plasma.
During the same period a new emerging field in plasma physics, viz. quantum plasmas, received widespread attention and interest. This is because of its broad applicability in micro- and nanomanufacturing. Work on the properties of degenerate ionized matter under the name quantum plasma has been inspired by the pioneering works of Bohm & Pines (Reference Bohm and Pines1953) and Levine & Roos (Reference Levine and Roos1962). Quantum electronic transport effects play a crucial role in metallic and semiconductor nanostructured materials, such as nanoparticles, quantum wells, quantum dots, quantum wires, carbon nanotubes and quantum diodes, nonlinear optics, laser experiments, etc., in which the electrons and holes can be regarded as quantum degenerate ingredients (Markowich, Ringhofer & Schmeiser Reference Markowich, Ringhofer and Schmeiser1990; Leontovich Reference Leontovich1994; Glenzer et al. Reference Glenzer, Gregori, Lee, Rogers, Pollaine and Landen2003; Shpatakovskaya Reference Shpatakovskaya2006; Ang & Zhang Reference Ang and Zhang2007; Brodin, Marklund & Manfredi Reference Brodin, Marklund and Manfredi2008; Shaikh & Shukla Reference Shaikh and Shukla2008; Glenzer & Redmer Reference Glenzer and Redmer2009). Quantum effects are also one of the main ingredients of nonlinear processes in ultradense plasma environments such as white dwarfs, active galactic nuclei, neutron stars, and many other dense astrophysical environments (Silva et al. Reference Silva, Bingham, Dawson, Mendonca and Shukla1999).
There are many mathematical methods to investigate the linear and nonlinear properties of charged particles at quantum levels in a dense degenerate plasma. However, the well-known mathematical approaches used for the quantum plasmas are the Wigner–Poisson, the Schrödinger–Poisson, and the Dirac–Maxwell models, which describe the statistical and hydrodynamic behaviours of the plasma particles at quantum scales. The quantum hydrodynamic (QHD) model is a useful approximation to study short-scale collective phenomenon such as waves, instabilities and nonlinear structures, etc. in quantum plasmas (Manfredi & Hass Reference Manfredi and Hass2001; Hass et al. Reference Hass, Garcia, Goedert and Manfredi2003; Ali et al. Reference Ali, Moslem, Shukla and Schlickeiser2007). The QHD model generalizes the fluid model with the inclusion of quantum statistical pressure and quantum diffraction (also known as Bohm potential) terms. The creation of pair plasmas surrounding neutron stars can be viewed as a collective quantum plasma effect. A dense fullerene-pair plasma in the laboratory has recently been reported (Oohara & Hatakeyama Reference Oohara and Hatakeyama2003; Oohara et al. Reference Oohara, Date and Hatakeyama2005; Oohara & Hatakeyama Reference Oohara and Hatakeyama2007) and the existence of nonlinear waves in such an environment has been confirmed experimentally.
So there is considerable interest in a model which takes into account both collective charged particle effects and quantum phenomena (Haas, Manfredi & Feix Reference Haas, Manfredi and Feix2000; Ali & Shukla Reference Ali and Shukla2007; Chatterjee, Ghorui & Wong Reference Chatterjee, Ghorui and Wong2011; Mushtaq & Vladimirov Reference Mushtaq and Vladimirov2011; Iqbal Reference Iqbal2013). In view of wide applications in dense astrophysical environments as well as in intense laser produced plasmas, Misra (Reference Misra2009) studied the formation of ion acoustic shock-like oscillations in quantum PI plasmas. Brodin & Marklund (Reference Brodin and Marklund2007) studied spin solitons in magnetized pair plasmas. Rasheed, Tsintsadze & Murtaza (Reference Rasheed, Tsintsadze and Murtaza2011) studied ion acoustic solitary waves in ultra-relativistic degenerate PI plasmas. In this paper, by employing the quantum hydrodynamical equations together with the Poisson equation, we study the properties of the IAWs in quantum PI plasmas. The quantum mechanical effects are examined for fully nonlinear IAWs. The plan of the paper is as follows. Governing equations and nonlinear structures are presented in § 2. In § 3 small-amplitude solitary wave solutions are given. In § 4 nonlinear analysis and numerical results are given, while § 5 is the conclusion.
2. Governing equations and nonlinear structures
We consider an unmagnetized and homogeneous quantum plasma comprising electrons, and positive and negative ions. The nonlinear dynamics of quantum IAWs is governed by (Hass et al. Reference Hass, Garcia, Goedert and Manfredi2003; Misra Reference Misra2009)
In the above equations, the ion number density
$n_{j}$
is normalized by its equilibrium value
$n_{j0}$
, the ion fluid speed
$u_{j}$
is normalized by
$C_{s}=(k_{B}T_{Fe}/m_{-})^{1/2}$
, where
$j=e,+,-$
, and the wave potential
${\it\phi}$
is normalized by
$k_{B}T_{Fe}/e$
, where
$k_{B}$
is the Boltzmann constant and
$T_{Fe}$
is the electron Fermi temperature. The time and space variables are normalized by the plasma period
${{\it\omega}_{Pj}}^{-1}=(m_{j}/4{\rm\pi}n_{j0}e^{2})^{1/2}$
and the Debye radius
${\it\lambda}_{D}=(k_{B}T_{Fe}/4{\rm\pi}n_{j0}e^{2})^{1/2}$
, respectively. Here we assume that the ions are cold, and the electrons obey the equation of state pertaining to a one-dimensional Fermi gas, given by
$p_{e}=(m_{e}v_{Fe}^{2}/3n_{e0}^{2})n_{e}^{3}$
, and we introduce the non-dimensional quantum parameter
$H=\hbar{\it\omega}_{pe}/k_{B}T_{Fe}$
. Here,
$v_{Fe}$
is the electron Fermi velocity, connected to the Fermi temperature
$T_{Fe}$
by
$m_{e}v_{Fe}^{2}/2=k_{B}T_{Fe}$
. Finally,
${\it\mu}=n_{e0}/Z_{-}n_{-0}$
,
${\it\beta}=Z_{+}n_{+0}/Z_{-}n_{-0}$
, so
${\it\mu}={\it\beta}-1$
, and
${\it\alpha}=Z_{+}m_{-}/Z_{-}m_{+}$
.
To investigate the linear properties of quantum IAWs in PI plasma, we introduce linear perturbations such as
$n_{e}=1+{\it\epsilon}n_{e}^{(1)},n_{+}=1+{\it\epsilon}n_{+}^{(1)},n_{-}=1+{\it\epsilon}n_{-}^{(1)},u_{+}=0+{\it\epsilon}u_{+}^{(1)},u_{-}=0+{\it\epsilon}u_{-}^{(1)},{\it\phi}=0+{\it\epsilon}{\it\phi}^{(1)}$
in the set of equations (2.7)–(2.12).
Now, assuming the plane wave solution of the form
$\exp [\text{i}(kx-{\it\omega}t)]$
, where
$k$
is the wavenumber and
${\it\omega}$
is the frequency, we obtain the dispersion relation as
$$\begin{eqnarray}{\it\omega}^{2}=\frac{\displaystyle k^{2}(1+{\it\alpha}{\it\beta})\left(2+\frac{H^{2}k^{2}}{4{\it\mu}}\right)}{\displaystyle 1+k^{2}\left(2+\frac{H^{2}k^{2}}{4{\it\mu}}\right)}.\end{eqnarray}$$
From (2.13) it is seen that the phase velocity is dependent on the quantum correction and other plasma parameters, such as positive to negative ion density ratio
${\it\beta}$
etc. Figure 1 shows the linear variation of normalized wave frequency
${\it\omega}$
as a function of normalized wavenumber
$k$
for different values of
$H$
and
${\it\beta}$
. It is seen that the wave frequency of the IAW excitations increases with increasing
$H$
and
${\it\beta}$
.
Plot of dispersion relation (2.13) for (a) several values of
$H$
:
$H=0.5$
(solid line),
$H=0.3$
(dashed line),
$H=0.1$
(dotted line), where
${\it\alpha}=2.0$
,
${\it\beta}=1.01$
; and (b) several values of
${\it\beta}$
:
${\it\beta}=1.51$
(solid line),
${\it\beta}=1.31$
(dashed line),
${\it\beta}=1.01$
(dotted line), where
${\it\alpha}=2.0$
,
$H=0.1$
.

To study the arbitrary-amplitude IAWs, we suppose that all the quantities depend on
${\it\xi}=x-Mt$
, where
$M$
is the Mach number defined as
$M=V/C_{s}$
and
$V$
is the velocity of the nonlinear structure, as seen in an inertial frame. Defining
$n_{e}=A^{2}$
, from (2.7)–(2.12) we obtain the system of second-order differential equations:
3. Small-amplitude solitary waves
For small amplitude, with the help of (2.14) and (2.15) after some straightforward mathematical manipulation the energy equation can be written as
where the Sagdeev (Reference Sagdeev1966) pseudopotential
${\it\psi}({\it\phi})$
is given by (keeping terms up to
${\it\phi}^{3}$
)
with
and
where
$$\begin{eqnarray}\displaystyle & \displaystyle a_{1}=\frac{\displaystyle \frac{{\it\alpha}{\it\beta}}{2M^{2}}+\frac{1}{2M^{2}}+\frac{4{\it\mu}}{H^{2}}\pm \sqrt{\left(\frac{{\it\alpha}{\it\beta}}{2M^{2}}+\frac{1}{2M^{2}}+\frac{4{\it\mu}}{H^{2}}\right)^{2}-4\frac{{\it\mu}^{2}}{H^{2}}}}{2{\it\mu}}, & \displaystyle\end{eqnarray}$$
$$\begin{eqnarray}\displaystyle & \displaystyle a_{2}=\frac{\displaystyle \frac{2{\it\mu}}{H^{2}}(10a_{1}^{2}-a_{1})-{\it\mu}a_{1}^{3}-\left(\frac{{\it\alpha}^{2}{\it\beta}}{2M^{4}}-\frac{1}{2M^{4}}\right)a_{1}}{\displaystyle 10{\it\mu}a_{1}-8\left(\frac{{\it\alpha}{\it\beta}}{2M^{2}}+\frac{1}{2M^{2}}\right)-\frac{8{\it\mu}}{H^{2}}}. & \displaystyle\end{eqnarray}$$
The soliton solution of (3.1) is given by
For real solutions in (3.7), we require that
$F_{1}<0$
and
$F_{2}$
is non-zero (since
${\it\phi}\rightarrow 0$
as
${\it\xi}\rightarrow \pm \infty$
). Figure 2(a) shows the behaviour of the pseudopotential for several values of
${\it\beta}$
. It is observed that the soliton amplitude increases as
${\it\beta}$
increases. Also, there exists a critical value of
${\it\beta}$
beyond which the soliton ceases to exist. Figure 2(b) depicts the soliton solution given in (3.7). It is clear that compressive potential pulses become more spiky (i.e. taller and narrower) with the increase of
${\it\beta}$
.
(a) Pseudopotential and (b) corresponding soliton solution for the plasma system for several values of
${\it\beta}$
:
${\it\beta}=1.5$
(solid line),
${\it\beta}=1.51$
(dashed line),
${\it\beta}=1.52$
(dotted line),
${\it\beta}=1.53$
(dot-dashed line), where
${\it\alpha}=4.0$
,
$H=0.2$
,
$M=5.3$
.

4. Nonlinear analysis and numerical simulation results
In this section, we consider (2.16)–(2.19) as a nonlinear dynamical system. So, we determine the equilibrium points of the nonlinear system and then determine their stability nature. The equilibrium points of the system (2.16)–(2.19) are given by
whence
${\it\phi}_{0}=0$
, or given by the roots of the equation
The variational matrix at the equilibrium point
$(A_{0},0,{\it\phi}_{0},0)$
is given by
$$\begin{eqnarray}\unicode[STIX]{x1D648}_{var}=\left(\begin{array}{@{}cccc@{}}0 & 1 & 0 & 0\\ {\it\Delta}_{1} & 0 & \displaystyle -\frac{2{\it\mu}A_{0}}{H^{2}} & 0\\ 0 & 0 & 0 & 1\\ 2{\it\mu}A_{0} & 0 & {\it\Delta}_{2} & 0\end{array}\right),\end{eqnarray}$$
where
${\it\Delta}_{1}=2{\it\mu}(5A_{0}^{4}-1-\,{\it\phi}_{0})/H^{2}$
and
${\it\Delta}_{2}=-{\it\alpha}{\it\beta}M/((M^{2}-2{\it\alpha}{\it\phi}_{0})^{3/2})-M/((M^{2}+2{\it\phi}_{0})^{3/2})$
.
The corresponding characteristic equation (assuming a linearized solution of the form
$\text{e}^{{\it\lambda}t}$
) is given by
Now, at the equilibrium point
${\it\phi}_{0}=0$
,
$A_{0}=1$
, (4.4) implies
where
$B=8{\it\mu}/H^{2}-(1+{\it\alpha}{\it\beta})/M^{2}$
and
$D=[8{\it\mu}/H^{2}+(1+{\it\alpha}{\it\beta})/M^{2}]^{2}-16{\it\mu}$
.
Case I:
$B>0$
. This occurs when
${\it\mu}>0$
and
$|(1+{\it\alpha}{\it\beta})|<|((8{\it\mu})/H^{2})M^{2}|$
.
Subcase I:
$B>\sqrt{D}$
. In this case the eigenvalues of
$\unicode[STIX]{x1D648}_{var}$
are given by
${\it\lambda}=\pm \sqrt{(B+\sqrt{D})/2}$
and
${\it\lambda}=\pm \sqrt{(B-\sqrt{D})/2}$
. In this case the variational matrix has two positive eigenvalues and two negative eigenvalues, which implies that the equilibrium point
$(1,0,0,0)$
is a saddle point of the system.
Subcase II:
$0<B<\sqrt{D}$
. In this case the eigenvalues of
$\unicode[STIX]{x1D648}_{var}$
are given by
${\it\lambda}=\pm \sqrt{(B+\sqrt{D})/2}$
and a pair of imaginary values
${\it\lambda}=\pm \text{i}\sqrt{(\sqrt{D}-B)/2}$
. Since one eigenvalue of
$\unicode[STIX]{x1D648}_{var}$
is positive the equilibrium point
$(1,0,0,0)$
is unstable.
Case II:
$B<0$
. This is possible only when
$|(1+{\it\alpha}{\it\beta})|>|((8{\it\mu})/H^{2})M^{2}|$
since
${\it\mu}$
cannot be negative.
Subcase I:
$-\sqrt{D}<B<0$
. In this case
$B<\sqrt{D}$
and the eigenvalues of
$\unicode[STIX]{x1D648}_{var}$
are given by
${\it\lambda}_{1,2}=\pm \sqrt{(B+\sqrt{D})/2}$
and
${\it\lambda}_{3,4}=\pm \text{i}\sqrt{(-B+\sqrt{D})/2}$
. The equilibrium point is unstable since
$\unicode[STIX]{x1D648}_{var}$
has one positive eigenvalue.
Subcase II:
$B<-\sqrt{D}<0$
. In this case
$B<\sqrt{D}$
and the eigenvalues of
$\unicode[STIX]{x1D648}_{var}$
are two pairs of imaginary numbers given by
${\it\lambda}_{1,2}=\pm \text{i}\sqrt{(-B+\sqrt{D})/2}$
and
${\it\lambda}_{3,4}=\pm \text{i}\sqrt{(-B-\sqrt{D})/2}$
. Therefore, there is a possibility of Hopf bifurcation in the system. Numerical simulation results are given below.
We have solved the system of differential equations (2.16)–(2.19) numerically with
${\it\alpha}=4.0$
,
${\it\beta}=1.01$
, and
$H=0.2$
, and corresponding phase diagrams as well as Poincaré sections are shown for different values of
$M$
in phase plane
${\dot{A}}{-}\dot{{\it\phi}}$
in figures 3 and 4. The technique of Poincaré surface section diagrams has been very helpful in studying qualitative properties of a dynamical system, as it allows one to trace the properties of periodic and quasi-periodic orbits of the original higher-dimensional system, as projected on a lower-dimensional space (Poincaré surface). In the Poincaré map, an unstable periodic orbit turns into a set of saddle points with their associated stable and unstable manifolds. The stable manifold is a curve in the phase space on which each initial condition converges to a saddle point in forward time dynamics. The unstable manifold is a curve whose points converge to a saddle point in the time-reversed dynamics (Alligood, Sauer & Yorke Reference Alligood, Sauer and Yorke1996). Most initial conditions in the close vicinity of a saddle point are repelled from it.
(a) Phase portrait and (b) Poincaré section of the given system for
$M=9.0$
with
${\it\alpha}=4.0$
,
${\it\beta}=1.01$
, and
$H=0.2$
.

We have plotted the phase portrait and Poincaré map of the system for
$M=9.0$
in figure 3. The existence of quasi-periodic behaviour is clear from the return map of
$\dot{{\it\phi}}$
in figure 3 for
$M=9.0$
. A quasi-periodic motion of a system is composed of incommensurable periodic motions and the trajectory in phase space winds around on a torus filling its surface densely. The return map data lie on smooth closed curves, confirming the existence of quasi-periodic behaviour of the system for
$M=9.0$
. In figure 4 the phase diagram and Poincaré map of the system are presented for
$M=2.0$
. The irregular set of points in the whole Poincaré plane guarantees the existence of chaos in the system for
$M=2.0$
. Chaos is aperiodic long-term behaviour of a system which has sensitive dependence on initial conditions. In the presence of chaos a small change in initial conditions causes unpredictable variation of oscillation pattern of the state variables. Therefore state variables have unpredictable bounded oscillation in the phase space for a chaotic system. We observe quasi-periodic and chaotic behaviour of the system for different values of
$M$
.
The phase diagram and Poincaré map of the system with
${\it\alpha}=4.0$
,
${\it\beta}=1.01$
,
$M=5.0$
and for different
$H$
, in the
${\it\phi}{-}A$
plane, are shown in figure 5 and figure 6. The phase diagram and corresponding Poincaré section for
$H=0.2$
are presented in figure 5. The quasi-periodic behaviour of the system is clear from the Poincaré section. The phase diagram of the system and corresponding Poincaré section are depicted in figure 6 for
$H=0.02$
. The Poincaré section confirms the existence of chaos in the system. It is also observed from numerical analysis that the dynamical behaviour does not change significantly due to variation of
${\it\beta}$
. Therefore, quasi-periodic as well as chaotic oscillations are possible in the present plasma system with the variation of Mach number and quantum parameter.
(a) Phase portrait and (b) Poincaré section of the given system for
$M=2.0$
with
${\it\alpha}=4.0$
,
${\it\beta}=1.01$
, and
$H=0.2$
.
(a) Phase portrait and (b) Poincaré section of the given system for
$H=0.2$
with
${\it\alpha}=4.0$
,
${\it\beta}=1.01$
, and
$M=5.0$
.
(a) Phase portrait and (b) Poincaré section of the given system for
$H=0.02$
with
${\it\alpha}=4.0$
,
${\it\beta}=1.01$
, and
$M=5.0$
.

5. Conclusion
In this paper, we have addressed the problem of nonlinear dynamics of IAWs in a three-component quantum plasma consisting of electrons, and positive and negative ions. By employing the QHD formulation, we have derived a set of coupled equations for arbitrary-amplitude IAWs and analysed them numerically. The Sagdeev pseudopotential technique is used to derive the energy equation to study the soliton solution, without assuming the quasi-neutral condition. The pseudopotential could not be obtained in the usual way, but a mechanism was found by which one can obtain the pseudopotential for small amplitude. We analytically find the equilibrium points of the system and determine their stability. We have shown the existence of quasi-periodic as well as chaotic motion in the system for different parameter values. The behaviour of the system depends on the plasma parameters
${\it\beta}$
,
$M$
, and the quantum parameter
$H$
. Quasi-periodic and chaotic dynamics are possible in the present plasma system. The results could be important for laser-produced plasmas in the laboratory as well as in dense astrophysical environments.




