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Inertial coalescence of drops with some viscosity

Published online by Cambridge University Press:  12 April 2024

Edward Beaty*
Affiliation:
Department of Applied Mathematics and Theoretical Physics, University of Cambridge, Cambridge CB3 0WA, UK
John R. Lister
Affiliation:
Department of Applied Mathematics and Theoretical Physics, University of Cambridge, Cambridge CB3 0WA, UK
*
†Email address for correspondence: edward.beaty4@gmail.com

Abstract

When two fluid drops touch, they coalesce due to surface tension. At early times, there is only a relatively small fluid bridge joining the drops. An asymptotic solution is presented for an inertial regime of early-time coalescence, in which inertial forces balance surface tension at leading order. It is demonstrated that viscosity nevertheless has a leading-order effect. Radial momentum is created at the tightly curved edge of the fluid bridge by the net force $2\gamma$ (per unit length) due to surface tension. This momentum is left behind the radially expanding bridge edge in a thin viscous wake. The divergent volume flux in the wake entrains fluid from above and below the bridge, and drives an inviscid irrotational flow in the drops on the scale of the bridge radius. This flow widens the gap between the drops ahead of the bridge, and the larger gap width results in a lower rate of coalescence. Including viscosity in this way improves the agreement between theory and the available experimental and numerical data.

Information

Type
JFM Papers
Creative Commons
Creative Common License - CCCreative Common License - BY
This is an Open Access article, distributed under the terms of the Creative Commons Attribution licence (http://creativecommons.org/licenses/by/4.0), which permits unrestricted re-use, distribution and reproduction, provided the original article is properly cited.
Copyright
© The Author(s), 2024. Published by Cambridge University Press.
Figure 0

Figure 1. (a) Geometrical definition sketch for early-time coalescence between two initially spherical drops of radius $a$ showing the hierarchy of length scales. The drops are joined axisymmetrically in the plane $z=0$ of cylindrical polar coordinates $(r,\theta,z)$ by a fluid bridge of radius $r_b(t)\ll a$. The edge of the bridge is tightly curved on a scale $|r-r_b|\sim r_c\ll r_b$. Ahead of the bridge, the drops are separated by a thin gap of width $2h(r,t)\ll r_b$. (b) Sketch of the flow structure in the inertial regime. The net force $2\gamma$ (per unit length into the page) from the edge creates radial momentum, which is left in a viscous wake over the fluid bridge. Entrainment into the wake with velocity $W$ drives an outer irrotational flow on the fluid-bridge scale, which widens the gap width $2h$ ahead of the fluid bridge.

Figure 1

Figure 2. A vertically integrated area element in the viscous wake between $r$ and $r+\delta r$, where $\delta r \ll r$, with angular extent $\delta \theta \ll 1$. The radial flow through the wake gives a vertically integrated flux $Q(r)=2 \gamma / \rho \, U(r)$ at $r$, which is multiplied by the length $r\,\delta \theta$ in the azimuthal direction to give a volume flux. The difference between the volume fluxes at $r$ and $r+\delta r$ is balanced by entrainment into the element with vertical velocity $u_z=- W(r)$ from above, and $+W(r)$ from below, which is multiplied by the area $r\, \delta \theta \, \delta r$ to give the volume flux.

Figure 2

Figure 3. A sketch of the boundary-value problem (3.4) and (3.5). The equations for the potential $\psi$ represent irrotational flow in $z>0$ subject to boundary conditions $u_z=-W$ in $r< r_b$, and $p=0$ in $r>r_b$.

Figure 3

Figure 4. Streamlines of the inviscid entrainment-driven flow (3.12).

Figure 4

Figure 5. Numerical and theoretical results for the streamlines (black lines) and surface profile (blue lines) in the case $\textit {Oh} = 0.001$ for $r_b = 0.03 a$. (a) Contours of the Stokes streamfunction (not equally spaced) and the surface profile found numerically by AHB (see their figure 8a). (b) Composite streamlines given by the external streamfunction (3.12) plus, for the flow in the wake, the Gaussian profile produced by vertical diffusion of momentum over the time $\tau (r)$ since it was left behind by the advancing edge of the fluid bridge. Curves $z = \pm 2 (\nu \tau )^{1/2}$ (red dashed lines) represent a diffusive scaling for the width of the wake. The surface profile includes the opening (4.4).

Figure 5

Figure 6. The theoretical surface profile ahead of the fluid bridge for $\textit {Oh}\ll 1$ and $r\ll r_b$ (dashed red line) obtained by adding the entrainment-driven opening (4.4) for $D=2^{1/2}$ to the initial surface profile $r^2/2a$ (blue dotted line). Also shown are numerically obtained surface profiles ahead of the fluid bridge for the cases $\textit {Oh} = 0.001$ at $r_b = 0.008a$ (solid line; see figure 9 of AHB) and $\textit {Oh} = 0.01$ at $r_b \approx 0.078a$ (short-dashed line; see figure 10 of SS14). The theoretical prediction does not include the rounding of the profile tip on a radial length scale $r-r_b=O(r_b^2/a)$, which can be seen in the numerical solutions and in a 1 : 1 plot of the shape (inset).

Figure 6

Figure 7. The constant $D$ for the fluid-bridge radius $r_b = D (\gamma a /\rho )^{1/4}t^{1/2}$ in the inertial regime. Experimental results of PBN (dots and error bars) for various Ohnesorge numbers $\textit {Oh}$ and the numerical value $D=1.5$ from SS14 (dashed line) are shown alongside our theoretically predicted value $D= 2^{1/2}$ (blue line) and, for comparison, the value $D= 2^{3/4}$ (red line) obtained by omitting entrainment.