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Competition of small targets in planar domains: from Dirichlet to Robin and Steklov boundary condition

Published online by Cambridge University Press:  12 January 2026

Denis S. Grebenkov
Affiliation:
CNRS – Université de Montréal CRM – CNRS, Montréal, QC, Canada Laboratoire de Physique de la Matière Condensée (UMR 7643), CNRS – Ecole Polytechnique, Institut Polytechnique de Paris, Palaiseau, France
Michael Jeffrey Ward*
Affiliation:
Department of Mathematics, University of British Columbia, Vancouver, BC, Canada
*
Corresponding author: Michael Jeffrey Ward; Email: ward@math.ubc.ca
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Abstract

We consider steady-state diffusion in a bounded planar domain with multiple small targets on a smooth boundary. Using the method of matched asymptotic expansions, we investigate the competition of these targets for a diffusing particle and the crucial role of surface reactions on the targets. We start from the classical problem of splitting probabilities for perfectly reactive targets with Dirichlet boundary conditions and improve some earlier results. We discuss how this approach can be generalised to partially reactive targets characterised by a Robin boundary condition. In particular, we show how partial reactivity reduces the effective size of the target. In addition, we consider more intricate surface reactions modelled by mixed Steklov-Neumann or Steklov-Neumann-Dirichlet problems. We provide the first derivation of the asymptotic behaviour of the eigenvalues and eigenfunctions for these spectral problems in the small-target limit. Finally, we show how our asymptotic approach can be extended to interior targets in the bulk and to exterior problems where diffusion occurs in an unbounded planar domain outside a compact set. Direct applications of these results to diffusion-controlled reactions are discussed.

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This is an Open Access article, distributed under the terms of the Creative Commons Attribution licence (https://creativecommons.org/licenses/by/4.0/), which permits unrestricted re-use, distribution and reproduction, provided the original article is properly cited.
Copyright
© The Author(s), 2026. Published by Cambridge University Press
Figure 0

Figure 1. Illustration of a bounded domain Ω⊂R2$\Omega \subset {\mathbb{R}}^2$ with a smooth boundary ∂Ω$\partial \Omega$ split into three absorbing patches Γεi$\Gamma _{\varepsilon _i}$ of length 2εi$2\varepsilon _i$ (in red and blue), and the remaining reflecting part ∂Ω0$\partial \Omega _0$ (grey dashed line). For a particle starting from a point x∈Ω${{\boldsymbol{x}}}\in \Omega$, the splitting probability S1(x)$S_1({{\boldsymbol{x}}})$ is the probability of hitting the blue patch Γε1$\Gamma _{\varepsilon _1}$ first.

Figure 1

Figure 2. Splitting probability S1(x)$S_1({{\boldsymbol{x}}})$, given by Eq. (2.30), for the unit disk with two Dirichlet patches of length 2ε1=0.2$2\varepsilon _1 = 0.2$ (red) and 2ε2=0.4$2\varepsilon _2 = 0.4$ (blue). Note that S1(x)$S_1({{\boldsymbol{x}}})$ was capped by 0$0$ and 1$1$, i.e., we plotted max{0,min{1,S1(x)}}$\max \{0, \min \{1, S_1({{\boldsymbol{x}}})\}\}$.

Figure 2

Figure 3. (a) Function C(μ)${\mathcal{C}}(\mu )$ from Eq. (3.7), in which the infinite series is truncated either to 50 terms (solid line) or to 10 terms (crosses), to highlight the accuracy of both truncations. Filled circles indicate the values −μ2k$-\mu _{2k}$, at which C(μ)${\mathcal{C}}(\mu )$ diverges. Dash-dotted line outlines the asymptotic limit ln⁡(2)$\ln (2)$ of C(μ)${\mathcal{C}}(\mu )$ as μ→∞$\mu \to \infty$. (b) Comparison of C(μ)${\mathcal{C}}(\mu )$ and its approximation (3.10), which is accurate over a broad range of μ$\mu$.

Figure 3

Figure 4. The ratio of C(μ)${\mathcal{C}}(\mu )$ with its approximation (3.10) is very close to unity on the range 0<μ<1$0\lt \mu \lt 1$.

Figure 4

Figure 5. Volume-averaged splitting probability S¯1=χ1$\overline {S}_1 = \chi _1$ for the unit disk, calculated from (3.17b), with two patches of equal length 2ε=0.2$2\varepsilon = 0.2$ located at boundary points (±1,0)$({\pm} 1,0)$. Three curves correspond to three values of the reactivity parameter q2$q_2$ of the second patch. Symbols present the numerical solution of the BVP (2.1b) with Robin boundary condition (3.1) by a finite-element method in Matlab PDEtool, with the maximal mesh size 0.02$0.02$.

Figure 5

Figure 6. Illustration for the unit disk with Steklov and Dirichlet patches. (a) One Steklov patch of length 2ε1=0.4$2\varepsilon _1 = 0.4$ at x1=(1,0)${{\boldsymbol{x}}}_1 = (1,0)$ (blue) and one Dirichlet patch of length 2ε2=0.6$2\varepsilon _2 = 0.6$ (red), whose centre x2${{\boldsymbol{x}}}_2$ is at angle θ=2π/3$\theta = 2\pi /3$. (b) One Steklov patch of length 2ε1=2ε=0.2$2\varepsilon _1 = 2\varepsilon = 0.2$ at x1=(1,0)${{\boldsymbol{x}}}_1 = (1,0)$ (blue) and three Dirichlet patches of length 2εj=0.4$2\varepsilon _j = 0.4$ (red), whose centres xj${{\boldsymbol{x}}}_j$ are equally spaced on the boundary of the unit disk.

Figure 6

Figure 7. Dependence of 1/(ε1σ0)$1/(\varepsilon _1\sigma _0)$ on ε2$\varepsilon _2$ for the unit disk with a Steklov patch of length 2ε1$2\varepsilon _1$ (located at x1=(1,0)${{\boldsymbol{x}}}_1 = (1,0)$), and one Dirichlet patch of length 2ε2$2\varepsilon _2$, located at x2${{\boldsymbol{x}}}_2$. Symbols present the numerical solution by a FEM with the maximal mesh size hmax=0.005$h_{\textrm {max}} = 0.005$ and lines show Eq. (5.30). (a)x2=(0,1)${{\boldsymbol{x}}}_2 = (0,1)$ and three values of ε1$\varepsilon _1$: ε1=π/6$\varepsilon _1 = \pi /6$ (circles), ε1=π/12$\varepsilon _1 = \pi /12$ (squares), and ε1=π/24$\varepsilon _1 = \pi /24$ (triangles). (b)ε1=π/12$\varepsilon _1 = \pi /12$ and two locations of the Dirichlet patch: x2=(−1,0)${{\boldsymbol{x}}}_2 = ({-}1,0)$ (circles, θ=π$\theta = \pi$), and x2=(0,1)${{\boldsymbol{x}}}_2 = (0,1)$ (squares, angle θ=π/2$\theta = \pi /2$).

Figure 7

Figure 8. The eigenfunctions Vj$V_j$ restricted on the Steklov patch Γε1$\Gamma _{\varepsilon _1}$, for the unit disk with a Steklov patch of length 2ε1=π/12≈0.26$2\varepsilon _1 = \pi /12 \approx 0.26$ (located at x1=(1,0)${{\boldsymbol{x}}}_1 = (1,0)$), and one Dirichlet patch of length 2ε2=π/6≈0.52$2\varepsilon _2 = \pi /6 \approx 0.52$, located at x2=(−1,0)${{\boldsymbol{x}}}_2 = ({-}1,0)$. Filled circles present the numerical solution by a FEM with the maximal meshsize hmax=0.005$h_{\textrm {max}} = 0.005$, while solid lines show Eq. (5.19) for j=0$j = 0$ and Eq. (5.24) for j>0$j \gt 0$. Four panels present the cases j=0,1,2,3$j = 0,1,2,3$.

Figure 8

Figure 9. Dependence of 1/(εσ0)$1/(\varepsilon \sigma _0)$ on ε$\varepsilon$ for the unit disk with one Steklov patch of length 2ε$2\varepsilon$ (located at x0=(1,0)${{\boldsymbol{x}}}_0 = (1,0)$), and N−1$N-1$ Dirichlet patches of length 4ε$4\varepsilon$, equally spaced on the boundary of the unit disk. Symbols present the numerical solution by a FEM with the maximal meshsize hmax=0.005$h_{\textrm {max}} = 0.005$ and lines show Eq. (5.38).

Figure 9

Figure 10. Dependence of 1/(ε1σ)$1/(\varepsilon _1 \sigma )$ on ε$\varepsilon$ for the unit disk with the Steklov patch of length 2ε1=0.2$2\varepsilon _1 = 0.2$ and 63$63$ Dirichlet patches (each of length 2ε$2\varepsilon$) that are equally spaced on the boundary of the unit disk. Filled circles correspond to κj$\kappa _j$ obtained via the discrete sum (5.38), the solid line indicates its large-N$N$ approximation (5.43), and the dashed line is the low-order approximation (5.44).

Figure 10

Figure 11. Illustration of a bounded domain Ω⊂R2$\Omega \subset {\mathbb{R}}^2$ with a smooth reflecting boundary ∂Ω0$\partial \Omega _0$ (grey dashed line) and three interior targets Ωεj$\Omega _{\varepsilon _j}$ (filled in grey), centred at xj${{\boldsymbol{x}}}_j$, with reactive boundaries Γεj$\Gamma _{\varepsilon _j}$ (in red and blue). For a particle started from a point x∈Ω${{\boldsymbol{x}}}\in \Omega$, the splitting probability S1(x)$S_1({{\boldsymbol{x}}})$ is the probability of hitting the boundary Γε1$\Gamma _{\varepsilon _1}$ first.

Figure 11

Figure 12. The asymptotic behaviour of the principal eigenvalue of the mixed Steklov- Neumann-Dirichlet problem, plotted as 1/(ε1σ0)$1/(\varepsilon _1\sigma _0)$ versus ε2$\varepsilon _2$, for the unit disk with two interior circular targets of radii ε1=0.05$\varepsilon _1 = 0.05$ and ε2$\varepsilon _2$ (variable from 0.01$0.01$ to 0.1$0.1$), located at x1=(−0.5,0)${{\boldsymbol{x}}}_1 = ({-}0.5,0)$ and x2=(0.5,0)${{\boldsymbol{x}}}_2 = (0.5,0)$. Filled circles present the numerical solution by a FEM with the maximal mesh size of 0.005$0.005$, solid line indicates Eq. (6.11).

Figure 12

Table B1. Comparison between the exact values of κj$\kappa _j$ from Eq. (2.41), their approximation (B.8), and its simpler asymptotic forms (B.11) and (B.12).Table B1 long description.

Figure 13

Figure B1. Exact values of κj$\kappa _j$ versus j/N$j/N$ on 0.2$0.2 \lt {j/N}\lt 0.5$ for N=64$N=64$ from Eq. (2.41), shown by filled circles, and their approximations (B.11, B.12, B.13) shown by lines.

Figure 14

Table C1. List of eigenvalues μ2k$\mu _{2k}$ and coefficients [Ψ2k(∞)]2$[\Psi _{2k}(\infty )]^2$ of the first 10 contributing terms in the spectral expansion (C.10) for C(μ)${\mathcal{C}}(\mu )$ (in addition, one has μ0=0$\mu _0 = 0$ and Ψ0(∞)=1/2$\Psi _0(\infty ) = 1/\sqrt {2}$). The reported values were obtained numerically by using a matrix representation of the Steklov problem in elliptic coordinates (see Appendix D). The matrix was truncated to the size 100×100$100 \times 100$ and then diagonalised numerically. The shown values did not change when the truncation order was increased to 500×500$500 \times 500$. For comparison, the large-k$k$ asymptotic approximations of μ2k$\mu _{2k}$ and [Ψ2k(∞)]2$[\Psi _{2k}(\infty )]^2$ from Eqs. (C.11, C.12) are also present. For completeness, we also present the first ten eigenvalues μ2k−1$\mu _{2k-1}$ that correspond to antisymmetric eigenfunctions Ψ2k−1$\Psi _{2k-1}$ that vanish at infinity.Table C1 long description.

Figure 15

Figure D1. The Steklov eigenfunctions Ψ2k(y1,0)$\Psi _{2k}(y_1,0)$, restricted onto the interval (−1,1)$({-}1,1)$, are shown by thick lines. These eigenfunctions are obtained by truncating the series in Eq. (D.2) to n≤100$n \leq 100$, with the coefficients ck,n$c_{k,n}$ found by diagonalising the truncated matrix M$\textbf{M}$ from Eq. (D.4). For comparison, functions cos⁡(πky1)$\cos (\pi k y_1)$ are plotted by thin lines.

Figure 16

Table F1. Summary of available formulas for various Neumann Green’s functions. Note that the surface Neumann Green’s function for rectangles can be derived from the results in [52, 61]. In turn, its extension to the exterior problem is not available.Table F1 long description.