1. Introduction
Radioactive and stable isotopes, and chemical tracers, are excellent time markers and climatic indicators which play an important role in the understanding of the past climatic, atmospheric, nuclear and chemical records from both polar and non-polar regions (Reference Delmas, Brait and LegrandDelmas and others, 1982; Reference Nijampurkar, Bhandari, Vohra and KrishnanNijampurkar and others, 1982; Reference Von Gunten, Rössler and GäggelerVon Gunten and others, 1983; Reference JouzelJouzel and others, 1987). Glaciers and ice caps located at high altitudes of remote areas in tropical latitudes may contain records extending back for periods of a few hundred to several thousands of years (Reference ThompsonThompson and others, 1990).
Earlier, long-lived radioisotopes, such as 32Si with a half-life of ∼ 140 years (Reference Somayajulu, Rengarajan, Lai, Weiss and CraigSomayajulu and others, 1987; Reference Hofmann, Bonani, Suter, Wolfli, Zimmermann and von GuntenHofmann and others, in press) and 210Pb (half-life = 22.3 year) have been used to estimate the ages of young and old ice of several Himalayan glaciers, using the standard radioactivity decay equation and a simple two-component flow model. These data, in turn, have been used for estimating surface and basal flow rates of the glacier ice (Reference Nijampurkar, Bhandari, Vohra and KrishnanNijampurkar and others, 1982; Reference NijampurkarNijampurkar, 1985). The artificial radionuclide 137Cs and total β activities, produced during atmospheric nuclear testing (1950–80) and during nuclear-reactor accidents such as Chernobyl in April 1986, can be used as time-markers to estimate accumulation rates of ice in glaciers (Reference Shukla, Bhandari, Nijampurkar, Rao, Puri and SharmaShukla and others, 1983; Reference Von Gunten, Rössler and GäggelerVon Gunten and others, 1983; Reference Pourchet, Pinglot, Reynaud and Holds-worthPourchet and others, 1988).
Using the isotopic composition of oxygen and hydrogen (δ18O and δD) as climatic indicators, much work has been done in polar and semi-polar regions, particularly in Greenland, Antarctica and the Alps (Reference Dansgaard, Johnsen, Meiler and LangwayDansgaard and others, 1969; Reference Ambach, Eisner and PesslAmbach and others, 1972; Reference Nijampurkar, Bhandari, Ramesh and BhattacharyaNijampurkar and others, 1986; Reference JouzelJouzel and others, 1987). The few stable isotopic studies that have been reported for the temperate (Himalaya) and sub-tropical (Dunde Ice Cap) regions indicate that these measurements can also be usefully applied to the study of climatic variations in these regions (Reference Grabczak, Niewodniczanski and RόżanskiGrabczak and others, 1983; Reference Nijampurkar and BhandariNijampurkar and Bhandari, 1984; Reference Thompson, Wu, Mosley-Thompson and XieThompson and others, 1988, Reference Thompson1990; Reference WakeWake, 1989).
Here, we report the results of isotopic studies on Chhota Shigri glacier and discuss them in relation to the pertinent glaciological parameters.
2. Location and Basic Features
Chhota Shigri glacier, located at 32°19′N, 77°31′E at an altitude of 4000–5660 m (Figs 1 and 2), is a valley-type glacier that lies on the northern ridge of the Pirpanjal range in the Lahul Spiti valley of Himachal Pradesh, Indian Himalaya. From its snout to the accumulation zone near Sara Umga Pass (4900 m), it extends for a distance of 9 km and its width varies from 3 to 1.5 km (Fig. 2). The glacier, located in a mountain range (4000–6000 m) composed mainly of crystalline granitic rocks, is about 10 km2 in area with an equilibrium line that reaches 4700 m a.s.l. The thickness of the glacier ice varies from 5 to 80 m between the snout and the accumulation zone; its average thickness is about 55 m.
Map showing the location of Chhota Shigri glacier, Himachal Pradesh, central Himalaya, India.
Sampling sites of snow, surface ice and a shallow ice core collected from Chhota Shigri glacier.
The tongue of the glacier for about 1 km above the snout is almost completely covered by surface moraines, while lateral moraines exist all the way along the glacier up to the accumulation zone (Reference Surendarkumar, Rai, Purohit, Rawat and MundepiSurenderkumar and others, 1987). Ablation in the middle and lower parts of the tongue is very intense. Meltwater from the glacier surface penetrates the ice body and forms subglacial channels, and a few surface meltwater channels are also observed along the sides of the glacier during the summer months. A depression near the snout gets filled with water during the ablation season to form a small supraglacial lake. Near the equilibrium line, old crevasses (generally 20–40 m in length) get filled and often the surface meltwater penetrates into the ice body to form subglacial channels. Near the equilibrium line in the accumulation zone, where the ice is subjected to considerable pressure, it cracks to form crevasses 40–100 m long along the length of the glacier. This crevassing makes the working conditions more difficult.
3. Meteorology, Hydrology and Glacio-Chemistry of the Glacier
The main valley (3000–7000 m deep), in which the glacier is situated, is dry. The annual precipitation on the glacier is 150–200 cm of snow (∼600 kg m−2year−1). During the year the temperature near the terminus varies from −15° to −5°C and near the snow line from 4° to −15°C. The annual 0°C isotherm is at an altitude of 4000 m. The average environmental lapse rate on Chhota Shigri glacier remained pseudo-adiabatic on most days during the summer and varied from 0.38° to 0.67°C/100 m (Reference Bhutiyani and SharmaBhuti-yani and Sharma, 1989).
The various positions of the snout line monitored during 1984–86 are an indication of the annual climatic variation on the glacier and have been accompanied by three main episodes of advance and retreat. Fluctuations of the equilibrium line, observed during the same period, support the above observations. The snout line of the glacier continued to recede at a rate of 18.7 m year−1 during 1986–88. This retreat was accompanied by a negative mass balance of 155 × 106 m3 year−1 observed during 1987–88.
The chemical composition of snow, surface ice, meltwaters and shallow ice cores has been studied to identify the different sources of origin of the major ions, such as Na, K, Mg and Cl, and the observed seasonal variations have been used to estimate the deposition rates of snow on Chhota Shigri glacier (Reference NijampurkarNijampurkar and others, 1990).
4. Sample Collection and Analytical Techniques
4.1. Sample Collection
During August 1987, we collected about 70 samples of snow, surface ice and shallow ice cores from both the accumulation and ablation zones of Chhota Shigri glacier (Fig. 2) for isotopic studies. These samples ranged from a few millilitres to a thousand litres depending upon the type of study envisaged. For dating snout ice, using cosmic-ray produced 32Si, we had to collect samples weighing 1000 kg due to the low specific activity of 32Si in natural waters.
In addition, we collected large volumes of meltwater from the snout (9001) and from an englacial stream (9501) located 100 m below the snout. Large plastic drums were used for this purpose. These natural waters were spiked with Na2SiO3 to raise the Si content of the waters to ∼ 10ppm. 32Si activities were scavenged from waters by using freshly precipitated Fe(OH)3 obtained by mixing a FeCl3 solution and NH4OH at a pH of 8 and stirring vigorously for a few hours (Reference NijampurkarNijampurkar, 1974; Reference Nijampurkar, Bhandari, Vohra and KrishnanNijampurkar and others, 1982). In this way, more than 90% of the SiO2 was physically adsorbed on to the Fe(OH)3 matrix which was then separated by decantation. After drying, the Fe(OH)3 was carefully transported to the laboratory. 2 litre samples of snow and surface-ice meltwater were collected at altitudes ranging from 4000 to 4900 m. Additional samples were also collected from a pit and shallow ice core (∼4 m depth) at an altitude of 4900 m in the accumulation zone for measurements of total β and artificial γ (137Cs) activities. For the stable-isotopic studies, the volumes of the samples collected were generally less than 10 ml.
4.2. Analytical Techniques
Radiochemical analysis of these samples was carried out in the laboratory using a variety of instruments including low-background Geiger Muller counters for 32P and total β-activity measurements, a high-efliciency well-type high-purity germanium (HPGe) detector system for γ-activity measurements and a mass spectrometer for stable-isotopic studies.
4.2(a). Radiochemical Purification and Assay of32p
Silica containing radioactive 32Si was separated from the Fe(OH)3 matrix using standard procedures (Reference Nijampurkar, Bhandari, Vohra and KrishnanNijampurkar and others, 1982) and was allowed to equilibrate with 32P, its daughter radioisotope, which is convenient to use due to its short half-life of 14.3 d. 33Si was counted via 32P (after radiochemical separation and purification as Mg2P2O7) on a low-background (1.5 eph) Geiger Muller counter with a NaI(T1) detector in anti-coincidence with a counting efficiency of 25%. The 32P activity was counted for several half lives (Fig. 3) and the initial 32Si activities were calculated.
Decay curve of32P for (a) meltwater and (b) the snout. The 32Si concentrations are calculated using the net 32P activity.
4.2(b). Total β-Activity Measurements
Melted samples of snow, surface ice and shallow ice cores ranging in volume from 1 to 2 1 were acidified with 1 :1 HNO3 and filtered to remove suspended dust. The filtrate was evaporated to dryness and its residue as well as the suspended dust were counted separately within a few weeks after collection to study the dissolved and adsorbed component on the dust of total β activity, on a low-background Geiger Muller counter, as described in section 4.2(a). Generally, ∼70% activity was observed in the solutions. However, the combined β activity of the dissolved and suspended components has been taken into account for calculations and discussions.
4.2(c). γ-Activity Measurements
A high-resolution and high-efficiency well-type germanium detector (130 cm3 volume) was used to obtain very low concentrations of 137Cs in snow and ice samples collected from Chhota Shigri glacier. The efficiency and resolution of the detector at 661.6 keV energy are 6.4% and 1.7 keV, respectively. Following the total β-activity measurements, the residue and the suspended dust were mixed together and counted for l37Cs activities in specially made plastic vials.
4.2(d). γ18O Measurements
Meltwater samples measuring about 10 ml were collected and transported in airtight plastic bottles to the laboratory where they were kept frozen to prevent evaporation until measurement. Oxygen-isotope analyses were carried out with a mass spectrometer (VG Micromass 602 D) at the Physical Research Laboratory using standard procedures (Reference Bhattacharya, Gupta and KrishnamurthyBhattacharya and others, 1985).
5. Results and Discussion
5.1. Dating of Glacier Snout Ice and Meltwater by 32Si
Using a half-life value of 140 years for 32Si (Reference Somayajulu, Rengarajan, Lai, Weiss and CraigSomayajulu and others, 1987; Reference Hofmann, Bonani, Suter, Wolfli, Zimmermann and von GuntenHofmann and others, in press) and assuming the average value of 32Si concentration in the snow precipitation in the Himalayan region to be 0.7 dpm/ 1031 (Reference Nijampurkar, Bhandari, Vohra and KrishnanNijampurkar and others, 1982), a radiometric age of 250 years for the snout ice is obtained, based on its measured 32Si concentration of 0.2 ± 0.02 dpm/1031 (Table 1). The basic assumption made in using the 32Si dating method is that the production rate as well as the fall-out of 32Si over the Himalyan region has remained constant over the past few centuries based on a fairly constant cosmic-ray flux during that period (Reference Lal and PetersLai and Peters, 1967).
32Si concentrations in snout and meltwater samples from Chhota Shigri glacier
Using the radiometric age of 250 years for the snout ice and the length of the glacier, the average surface ice-flow rate over the past few centuries is calculated to be 28 m year−1. Comparison with the modern surface ice-flow rate of 23 m year−1 based on conventional survey methods (personal communication from V. B. Bahuguna) indicates that the glacier is not in a steady state.
Using a measured 32Si concentration in the meltwater (sample CS-2, Table 1) of 0.47 ± 0.05 dpm/1031, the radiometric age of the average meltwater has been estimated to be 80 years. This suggests a mix of at least 55% snowmelt with ∼45% of old ice melt that emerges from the supraglacial lake of Chhota Shigri glacier.
5.2. Deposition of Chernobyl Fall-Out on Chhota Shigri Glacier
The artificial radioactivity discharged into the atmosphere following the Chernobyl accident of 26 April 1986 was deposited via precipitation and dry fall-out depending upon the extent of the atmospheric circulation pattern. Since 1986, radioactivity from Chernobyl has been monitored worldwide in aerosols, rainwater, fresh snow, ocean water, lake sediments and milk products (Reference Csongor, Kiss, Nyako and SomorjaiCsongar and others, 1986; Reference NishizawaNishizawa and others, 1986; Reference Ambach, Rehwald, Blumthaler and EisnerAmbach and others, 1987; Reference Mélières, Pourchet,, Pinglot, Bouchez and PibouleMélières and others, 1988; Reference Mitchell, Steele and SteeleMitchell and others, 1988; Reference Pourchet, Pinglot, Reynaud and Holds-worthPourchet and others, 1988).
5.2(a). Total β-Activity Measurements
The total β activities in snow, surface ice and shallow ice-core samples were measured within a few weeks of their collection and the results are given in Table 2. It appears that the total β activity (with an average value of 4100 dph l−1) measured in snow samples collected in the altitude range 4150–4650 m (see Fig. 4) is larger by a factor of about 8 than that observed in the surface-ice samples (∼ 500 dph l−1) collected from the same locations on the glacier. Although the peak total β activity (8400 dpl l−1) observed in the snow sample collected from an altitude of 4550 m is much higher (by a factor of about 17) than that observed in surface-ice samples, the activities observed during the present work in the Himalaya are lower by a factor of about 20 than those observed in the European Alps (Reference Ambach, Rehwald, Blumthaler, Eisner and BrunnerAmnbach and others, 1989).
Variations of total β and 137Cs activities (dph l−1) in snow and surface-ice samples from different altitudes on Chhota Shigri glacier. These activities are for fall-out deposited in the altitude range of 4150–4650 m. The dotted line shows the model curve for the deposition of Chernobyl fall-out on the glacier.
Deposition of total β and 137Cs activities at different altitudes on Chhota Shigri glacier
5.2(b). Artificial γ-Activity Measurements
A host of fission products (artificial radionuclides) like 144Ce, 137Cs, 134Cs, 125Sb, 103Ru, 95Zr, etc. were produced during the Chernobyl accident (Reference Sadasivan and MishraSadasivan and Mishra, 1986). Only 137Cs with a longer half-life (30 year) could be identified in the γ-ray spectrum of snow samples collected at different altitudes (Table 2).
137Cs activities in snow and surface-ice samples are given in Table 2. Values range from 10 to 255 dph l−1 in snow and from 10 to 27 dph l−1 in surface ice. It is evident from Figure 4b that the higher 137Cs activities occur in snow samples deposited in the altitude range of 4150–4650 m. Average value of 120 dph l−1 and a peak activity of 255 dph l−1 at 4550 m are higher by factors of about 7 and 15, respectively, than those measured in the surface-ice samples (17 and 27dph l−1, respectively). Surprisingly, we did not observe high total β and 137Cs activities in samples collected at different depths from a 1 m snow pit (4700 m) and a 4 m shallow ice core (4900 m) from the accumulation zone. These results support earlier findings on the distribution of total β activities on Chhota Shigri glacier, showing that the radioactive cloud bearing Chernobyl fall-out did not penetrate or diffuse beyond 4700 m altitude over the glacier and that its deposition in the Himalaya is much lower, by a factor of at least 15, than that deposited in the Swiss Alps (Reference Haeberli, Gäggeler, Baltensperger, Jost and SchottererHaeberli and others, 1988).
The depositional characteristics of Chernobyl fall-out on Chhota Shigri glacier can be explained in the following way. Snow deposited during the winter months in the accumulation zone survives the summer, lasting from April to October, whereas most of the snow deposited close to the equilibrium line (4700ma.s.l.) melts away in the summer. The snow that persists in the ablation zone until mid-summer (July-August) represents deposition that occurred in the early winter months of November and December, and which enabled us to monitor the Chernobyl fall-out in this region. However, near the snout region (4050 m), snow that falls early in the winter probably melts away due to higher temperatures over the thick debris cover. The snow that survives into midsummer was deposited later in the winter, i.e. from December to March, and as a result we could not observe any activity in the sample collected at 4050 m near the snout.
It has been observed that most of the Chernobyl fall-out was deposited in the regions immediately adjacent to the accident site in May 1986. The fall-out has been monitored at different locations up to an altitude of 4250 m in the European Alps (Reference Ambach, Rehwald, Blumthaler and EisnerArnbach and others, 1987, Reference Ambach, Rehwald, Blumthaler, Eisner and Brunner1989; Reference Haeberli, Gäggeler, Baltensperger, Jost and SchottererHaeberli and others, 1988; Reference Pourchet, Pinglot, Reynaud and Holds-worthPourchet and others, 1988). It is known from earlier studies (Reference Csongor, Kiss, Nyako and SomorjaiCsongar and others, 1986; Reference Fry, Clarke and O’RiordamFry and others, 1986) that the Chernobyl fall-out was scavenged mostly by the wet precipitation process and that scavenging by snowfall was found to be similar to that observed with wet precipitation. Additionally, it is observed that most of the radioactive fall-out (< 90%) occurred on a few rainy days or in snow that was deposited within a period of 2 weeks after the accident. Assuming that the same process dominates in the Himalaya, one would expect the Chernobyl fall-out to have been deposited with the snow that fell during November and December 1986.
A fraction of the radioactive plume must also have spread over the 30–40° N latitude belt over the Mediterranean Sea and subsequently was transported over the Himalayan region in the course of time along with the western winds and by a process of diffusion. It is difficult to know how long it should have taken for the radioactive-plume front carried by the winds to reach the Himalayan region. But, certainly, the radioactive clouds were transported to the Lahual Spiti valley (where Chhota Shigri glacier is situated), where fall-out on the glacier occurred either by a process of dry deposition of aerosols or in snow deposited during the early winter months (November-December).
The results of the present work confirm for the first time deposition of Chernobyl fall-out on Chhota Shigri glacier. The results also show that a very small fraction of the Chernobyl fall-out was deposited in the Himalaya compared to that in the Alps.
5.3. Isotopic Composition (δ18O) of Snow, Ice and Core Samples
The isotopic composition of snow deposited at high altitudes in the mountains depends primarily on the surface-air temperature, circulation pattern and the source of the moisture. The δ18O values of different samples obtained, in comparison with that of SMOW, are shown in Figures 5 and 6. The following observations emerge from the data.
5.3(a). δ18O Variation with Altitude in Snow and Ice
Figure 5 shows the results of the analyses of the snow and surface-ice samples collected at different altitudes, both in the accumulation and ablation zones of Chhota Shigri glacier. The snow samples span an elevation of about 700 m and show δ18O values fluctuating in the range −4 to −10‰ with a mean value of −7 ± 3‰. According to Reference Mitchell, Steele and SteeleNiewodniczanski and others (1981), no systematic dependence of δ18O on altitude is observed in the sampling range 4050–4750 m. Our observations are similar to those of Ambach and others (1986), Reference WushikiWushiki (1977) and Reference Nijampurkar, Bhandari, Ramesh and BhattacharyaNijampurkar and Bhandari (1984), which also fail to indicate any altitude dependence in isotopic fractionation. As expected, values are much higher than those observed in Changme Khangfu glacier, Sikkim valley (−19 ± 2‰), as the snow samples were collected from higher altitudes (4900–5400 m). δ18O values of the surface-ice samples collected from altitudes between 4100 and 4600 m range from −6 to −11‰ with a mean value of −8.5 ± 2.5‰. These values are again higher than those observed for surface-ice samples from Changme Khangfu glacier which range from −12 to −17‰ with an average value of −14.5 ± 2.‰.
Variation of δ18O in snow and surface-ice samples at different altitudes along the glacier. No systematic variation of δ18O is observed with altitude for the snow samples.
The average δ18O value of samples of snout ice is found to be −11 ± 0.1‰ which is the lowest of all the values so far observed on Chhota Shigri glacier. The radiometric age of the snout ice, based on 32Si measurements, has been estimated at 250 years. The data therefore indicate that climatic conditions two centuries ago were appreciably cooler than the present-day ones.
5.3(b). δ18O Variation in a Shallow Core
As discussed earlier, the snowfall on Chhota Shigri glacier generally takes place from November to March. The average surface-air temperatures for the period February and March are usually higher by about 14°C (personal communication from N.V. Apte, India Meteorology Department, New Delhi) than those during November-January. Accordingly, δ18O values of the snow deposited during February-March should, as observed in a 4 m core, be less negative by about 7‰ than those deposited during November-January.
The results of the δ18O measurements on samples from a shallow pit and core from 4.0 m depth at 4900 m in the accumulation zone of the glacier are shown in Figure 6. The δ18O values fluctuate between −1 and −9‰ with a mean value of −5.3‰. The peak values observed around 0.4, 1.7 and 3.0 m suggest annually repeating cycles of about 1.30 m of snow, equivalent to a deposition rate of snow of about 520 kg m−2 year−1. This value agrees reasonably well with the 600 kg m−2 year−1 estimated from the seasonal variations of major ions observed in the same ice core (Reference NijampurkarNijampurkar and others, 1990).
Depth profile of δ18O in a 4 m shallow ice core from an altitude of 4900 m in the accumulation zone. The deposition rate of snow has been estimated to be 520 kg m−2 year−1, using seasonal variations in δ18Ovalues.
6. Conclusions
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1. Using cosmogenic 32Si activities in precipitation and ice from the snout of Chhota Shigri glacier, the radiometric age of the snout ice has been estimated at ∼ 250 years. The average flow rate of the glacier over the past few centuries has been estimated at ∼ 28 m year−1.
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2. 32Si studies on englacial meltwaters indicate that they consist of at least 55% snow meltwater and 45% old-ice meltwater.
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3. The identification of the artificial radionuclide 137Cs in snow samples collected in August 1987 confirms the presence of Chernobyl fall-out on Chhota Shigri glacier, Indian Himalaya.
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4. The average δ18O value of snout ice is depleted by 5.7‰ compared to the average value obtained on a 4m shallow ice core. This ice core represents the snow accumulated in the 2 years prior to August 1987 which would indicate that the climatic conditions a few centuries ago were appreciably cooler than that at present.
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5. Based on δ18O variations in a shallow ice core, the snow accumulation on Chhota Shigri glacier, averaged for the 2 years prior to August 1987, has been calculated as 520 kg m−2 year−1.
Acknowledgements
This project was financed by the Indian Department of Science and Technology. We are especially grateful to Dr M.N. Qureshi of the Department of Science and Technology, New Delhi, and Dr Surendrakumar of the Wadia Institute of Himalayan Geology, leader of the expedition, and his colleagues for their kind help in collecting samples. We are also grateful to Professor B. L. K. Somayajulu for his co-operation during the work, Dr R. Ramesh for useful discussions and Mr R. A. Jani for δ18O measurements.
The accuracy of references in the text and in this list is the responsibility of the author, to whom queries should be addressed.
