Hostname: page-component-7b7567c8c-kwt9d Total loading time: 0 Render date: 2026-11-12T07:50:16.732Z Has data issue: false hasContentIssue false

Crystallography and morphology of a lathy ferrite in Fe–Cr–Ni alloys during directional solidification

Published online by Cambridge University Press:  24 July 2013

Junwei Fu*
Affiliation:
Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
Yuansheng Yang
Affiliation:
Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
*
a)Address all correspondence to this author. e-mail: hitfujw@163.com

Abstract

The relationship between morphology and crystallography of an entangled lathy ferrite during directional solidification in Fe–Cr–Ni alloy has been investigated. During solidification, morphology of the lathy ferrite depends on the orientation relationship between the lathy ferrite and austenite. When the plane in the austenite substrate is ${(1\bar 11)_{\rm{\gamma }}}$, “Y-shaped” lathy ferrite grows in an entangled cluster and the orientation relationship between the lathy ferrite and austenite is the Nishiyama–Wassermann relationship. Lathy ferrite is preferentially elongated along ${\langle 211\rangle _{\rm{\gamma }}}$ and ${\langle 011\rangle _{\rm{\gamma }}}$ directions on ${(1\bar 11)_{\rm{\gamma }}}$ plane due to lower misfit. The included angle among the “Y-shaped” lathy ferrite is about 120° because the angle between each pair of ${[21\bar 1]_{\rm{\gamma }}}$, ${[\bar 112]_{\rm{\gamma }}}$, and ${[\bar 1\bar 2\bar 1]_{\rm{\gamma }}}$ crystal directions is equal to 120°. Formation mechanism of the perpendicular lathy ferrite has also been analyzed according to the relationship between ${\langle 211\rangle _{\rm{\gamma }}}$ and ${\langle 011\rangle _{\rm{\gamma }}}$ on ${(1\bar 11)_{\rm{\gamma }}}$ plane. This indicates that required crystal morphology of the lathy ferrite in the solidified microstructure can be obtained by controlling the crystal plane of austenite.

Information

Type
Articles
Copyright
Copyright © Materials Research Society 2013 
Figure 0

FIG. 1.(a) As-quenched microstructure of Fe–Cr–Ni stainless steel during solidification (δ, γ, and L denote the entangled lathy ferrite, austenite, and quenched liquid, respectively) (“Y-shaped,” “V-shaped,” and perpendicular ferrites are denoted by circles) and (b) magnified image of the “Y-shaped,” “V-shaped,” and perpendicular ferrite morphologies.

Figure 1

FIG. 2.TEM micrograph of the entangled lathy ferrite and the SAD patterns of lathy ferrite and austenite. (a) TEM micrograph; (b) SAD patterns with [001]δ||[011]γ zone axis showing the orientation relationship between the lathy ferrite and austenite.

Figure 2

FIG. 3.TEM micrograph of the entangled lathy ferrite and the SAD patterns of lathy ferrite and austenite. (a) TEM micrograph; (b) SAD patterns with ${[\bar 110]_{\rm{\delta }}}$||${[1\bar 11]_{\rm{\gamma }}}$ zone axis showing the orientation relationship between the lathy ferrite and austenite.

Figure 3

FIG. 4.An overlapped stereographic projection of entangled lathy ferrite and austenite. (hkl) is the crystal plane of ferrite and (hkl) is the crystal plane of austenite.

Figure 4

FIG. 5.(a) Schematic diagram of the atomic arrangement along ${[21\bar 1]_{\rm{\gamma }}}$ direction in $(1\bar 11)$ plane of austenite; (b) schematic diagram of the atomic arrangement along ${[110]_{\rm{\delta }}}$ direction in $(\bar 110)$ plane of ferrite; (c) schematic diagram of the relationship between ${[21\bar 1]_{\rm{\gamma }}}$ and ${{\rm{[110]}}_{\rm{\delta }}}$ directions.

Figure 5

FIG. 6.X-ray diffraction patterns of the unmelted sample prior to solidification for Fe–Cr–Ni alloy, where only single austenite phase occurs.

Figure 6

FIG. 7.X-ray diffraction patterns of the directionally solidified sample for Fe–Cr–Ni alloy.

Figure 7

FIG. 8.(a) Schematic for the formation of 60°; (b) the case of parallel ferrite.

Figure 8

FIG. 9.Schematic for the formation of the perpendicular ferrite morphology.