1. Introduction
The South China Block and North China Block were sutured in the late Middle Triassic to Middle Jurassic period along the Qinling–Dabie and Sulu orogen (Zhang et al. Reference Zhang, Bai, Sun, Guo, Zhou and Li1985, Reference Zhang, Yu, Dong and Yao2000; Li, Reference Li, Flower, Chung, Lo and Lee1998; Grimmer et al. Reference Grimmer, Ratschbacher, McWilliams, Franz, Gaitzsch, Tichomirowa, Hacker and Zhang2003; Wang et al. Reference Wang, Wang, Jahn, Hu and Chen2007). The South China Block can be subdivided into two blocks: the Yangtze Block to the NW and the Cathaysia Block to the SE, which were connected by collision during the Proterozoic Grenvillian orogen (Charvet et al. Reference Charvet, Shu, Shi, Guo and Faure1996; Li, Reference Li, Flower, Chung, Lo and Lee1998) (Fig. 1a). The Mesozoic granite-volcanic rocks are widely distributed in the South China Block. These rocks occurred in different ages within the Mesozoic, with complex formation processes and close affinity with mineralization of W, Sn, U, Nb–Ta, etc. The Indosinian granites (210–250 Ma) are distributed inland, while the dominant Yanshanian granites (180–90 Ma) are distributed in the southeast of the South China Block. The Late Yanshanian granite-volcanic (140–90 Ma) rocks occupy about 139 920 km2, are genetically associated with active continental margin magmatism, and are distributed mostly in the coastal region (Fig. 1a). However, previous Mesozoic tectono-magmatism studies have concentrated on the southeast; the contemporaneous granites in the NE Yangtze Block (Yangzte foldbelt) deserve further study. The Yangtze foldbelt (Fig. 1a) strikes NE, and the stratified bedrock of this foldbelt comprises late Precambrian sedimentary and metamorphic rocks and Early Palaeozoic sandstone. The age of the basement beneath this foldbelt is uncertain, but Indosinian (Triassic period) and Yanshanian (Jurassic to Cretaceous period) thermal overprints have been identified (Yuan et al. Reference Yuan, Zhou, Yue, Zhu and Hou2003, Reference Yuan, Zhou, Fan, Yue, Zhu and Hou2006). The Yanshanian intermediate to silicic intrusions exposed in this foldbelt have been subdivided into several zones by Chen et al. (Reference Chen, Zhou, Li, Foland, Huang and Lu1993), for example, diorite–quartz diorite–granodiorite stocks along the Yangtze River, mostly associated with Cu, Fe and Au mineralization (the Yangtze zone), granodiorite–granite batholiths or large stocks further south and away from the Yangtze River (the Jiangnan zone).
(a) Distribution of Mesozoic granite-volcanic rocks in South China (modified from Zhou et al. Reference Zhou, Sun, Shen, Shu and Niu2006); (b) simplified geological map of the Jiuhuashan–Qingyang complex.
Based on Sr–Nd isotopic analysis of the intrusions, Chen, Zhou & Foland (Reference Chen, Zhou and Foland1985) and Chen et al. (Reference Chen, Zhou, Li, Foland, Huang and Lu1993) argued that (a) the granitoids of Jiangnan zone were formed by crustal anatexis and no mantle magmas were directly involved during the magmatism, (b) the isotopic characteristics of the intrusions are very similar to the nearby Proterozoic metamorphic rocks (Shangxi Group, 50 km away) and (c) the basement beneath the Yangtze foldbelt is Proterozoic in age. However, no Proterozoic basement has previously been identified in the Yangtze foldbelt. Therefore, the age spectra of inherited zircon grains within the granitoids in this foldbelt have become a subject of interest.
The Jiuhuashan–Qingyang complex is located within the Yangzte foldbelt. Early geological and petrological investigations of the complex (e.g. Wang, Liu & Peng, Reference Wang, Liu and Peng1965) revealed that the complex comprises a main body (the Qingyang granite) consisting of granodiorite and monzogranite, and a central body consisting mainly of alkali-feldspar granite (the Jiuhuashan granite). Geochronological investigations using 40Ar–39Ar and Sr–Nd isotopic techniques (Chen, Zhou & Foland, Reference Chen, Zhou and Foland1985; Chen, Foland & Zhou, Reference Chen, Foland, Zhou and Wu1985; Chen et al. Reference Chen, Zhou, Li, Foland, Huang and Lu1993) indicated that the Qingyang body was formed at 137.6 ± 1.4 Ma (Rb–Sr isochron method) and the Jiuhuashan body was formed at 122.7 ± 1.2 Ma (40Ar–39Ar method). However, the crystallization age of individual rock-types remains unclear.
Based on a new petrographical investigation, we carried out major and trace element analyses of representative granodiorite, monzogranite and alkali-feldspar granite, LA-ICPMS zircon U–Pb dating and CHIME dating in order to understand better the crystallization and the genetic relationship of different phases of the complex, while further constraining the characteristics of the magma source and tectonic setting by integration of regional data on Late Mesozoic granites in SE China.
2. General geology
The Jiuhuashan–Qingyang complex is located in South Anhui, and crops out over an area of approximately 750 km2. The complex intruded into the late Precambrian to Early Palaeozoic sandstones, shales and limestones. The first stage intrusion was named the Qingyang body, which in turn was intruded by the second stage central granite named the Jiuhuashan body. Finally, a series of porphyritic syenite dykes were emplaced mostly into the Qingyang body. A detailed petrographical study and geological mapping completed by Wang, Liu & Peng (Reference Wang, Liu and Peng1965) have been simplified as Figure 1b and indicate that the Jiuhuashan–Qingyang complex was formed in three stages.
The main Qingyang body can be further divided into two phases: a marginal granodiorite with fine to medium granitic texture and an inner medium-grained to porphyritic monzogranite. A swarm of quenched enclaves with typical chilled margins and back-veins infiltrated from host magma (Fig. 2) have been found in the northeast part of the Qingyang body. These fine-grained, igneous-textured enclaves are igneous in origin, and are usually interpreted as globules of a separate magma, mingled with the volumetrically dominant host magma.
Quenched enclaves found in the Qingyang body: (a) typical chilled margin; (b) back-vein. The ink pen is 14.5 cm long.
Modal mineral compositions of the complex are listed in Table 1. All granodiorite samples are medium-grained and lack foliation. Sample JH03 collected near the contact with monzogranite is more felsic than samples JH10 and JH11 away from the boundary. Hornblende is present in the granodioritic rocks but is sparse in the monzogranite. Monzogranite samples JH01 and JH02 were collected from an active quarry and are characterized by phenocrysts (5–10 mm) of pink-coloured microperthite.
The mineral constitutents of Jiuhuashan–Qingyang complex
In the second emplacement stage, the Jiuhuashan body, which crops out over about 100 km2, was emplaced as a N–S elongate body that cuts across the boundary between the granodiorite and monzogranite components of the first stage. The Jiuhuashan body is generally equigranular, of medium to coarse grain size, and is dominated by microperthite and quartz, with minor albite, biotite and accessory zircon, apatite, allanite, magnetite, thorite and fergusonite (Table 1). Five samples of alkali-feldspar granite (JH05, JH06, JH07, JH08 and JH09) were collected from the Jiuhuashan body during this study.
The third and final stage of magmatism is represented by the porphyritic syenite dykes, most of which have a graphic texture. The dykes range from several metres up to hundreds of metres in width and extend to kilometres in length, and most have a N–S strike. They are concentrated in the northern part of the complex and they intrude all the other phases of the complex. The Jiuhuashan granite may have been metasomatized following the emplacement of these dykes, resulting in the formation of albite granite. Microstructure investigations show that albite veins are commonly developed on primary K-feldspar, and therefore formed microperthite (Fig. 3a). Sometimes the fine-grained albites occur as rims around microperthite, implying that they are of metasomatic origin (Fig. 3b). In some samples, almost all of the microperthite has been replaced by albite (Wang, Liu & Peng, Reference Wang, Liu and Peng1965). The development of discrete albite suggests that the Jiuhuashan body underwent some metasomatic alteration after solidification.
Photomicrographs of metasomatized alkali-feldspar granite in cross-polarized transmitted light. Ab – albite; Per – microperthite.
3. Analytical methods
After petrographical examination, fresh rock samples were selected for zircon separation, major and trace element analyses. Major elements were determined on fused glass discs by a SHIMADZU XRF 1800 sequential X-ray fluorescence spectrometer (XRF) at the Center for Chronological Research, Nagoya University. The glass discs were prepared by fusion of a mixture with 0.7 g sample powder and 6.0 g lithium borate. Trace elements were analysed in the State Key Laboratory of Mineral Deposits Research, Nanjing University, China, by the solution method using a Finnigan Element II Inductively Coupled Plasma Mass Spectrometer (ICP-MS) (details of the analytical method are given by Jiang, Yu & Lu, Reference Jiang, Yu and Lu2004). Comparative analysis of fused glass samples was conducted in the same laboratory on an Agilent 7500a ICP-MS equipped with a New Wave Research 213 nm laser ablation system. Overall procedures used were similar to Norman et al. (Reference Norman, Pearson, Sharma and Griffin1996, Reference Norman, Griffin, Pearson, Garcia and O'Reilly1998), except for the laser system. The analyses were calibrated against the spiked silicate glass reference STD610; KL2-G was analysed to monitor accuracy.
Zircons were separated from four representative samples through standard density and magnetic separation techniques. Random zircon grains were hand-picked under a binocular microscope and mounted in a 1.4 cm diameter epoxy disc, and polished to expose the central parts of the crystals. In order to characterize the internal structures of the zircons and to choose appropriate target sites for U–Pb dating, backscattered electron (BSE) images were obtained using a JEOL JXA-8800 microprobe at Nanjing University with a 15 kV accelerating voltage and 20 nA beam current.
Zircon U–Pb analyses were carried out by LA-ICPMS on the Agilent 7500a at Nanjing University. Analyses were carried out with a beam diameter of 30–40 μm, 5 Hz repetition rate, and energy of 10–20 J·m−2. Data acquisition for each analysis took 120 s (40 s on background, 80 s on signal). Raw count rates for 206Pb, 207Pb, 208Pb, 232Th and 238U were collected for age determination. Mass discrimination of the mass spectrometer and residual elemental fractionation were corrected by calibration against a homogeneous standard zircon, GEMOC/GJ-1 (601 Ma). Samples were analysed in ‘runs’ of about 18 analyses, which include 10–12 unknowns, bracketed beginning and end by two to four analyses of the standard. The ‘unknowns’ include two analyses of the well-characterized Mud Tank zircon (735 Ma), which were analysed frequently to monitor the reproducibility and the stability of instrument. Details of instrument settings and analytical procedures followed Jackson et al. (Reference Jackson, Pearson, Griffin and Belousova2004).
Raw ICP-MS data were processed using the program GLITTER (van Achterbergh et al. Reference van Achterbergh, Ryan, Jackson, Griffin and Sylvester2001). Common Pb contents were evaluated using the method described by Andersen (Reference Andersen2002). Age calculations and concordia plots were made using Isoplot (ver. 2.49) (Ludwig, Reference Ludwig2001). The concentrations of U and Th in each analytical spot were derived by comparison of background-corrected count rates with mean count rates on the GJ-1 standard, which has well-defined concentrations of these two elements.
Zircon and monazite in JH08 alkali-feldspar granite were dated by the CHIME method (Chemical Th–U–total Pb Isochron Method: Suzuki & Adachi, Reference Suzuki and Adachi1991) using a JCXA-733 EPMA with 4 WDSs at the Center for Chronological Research, Nagoya University. Details of experimental techniques for CHIME dating were described in Suzuki & Kato (Reference Suzuki and Kato2008).
4. Results
4.a. Major element geochemistry
Eight representative fresh samples were selected for major element analysis and the results are listed in Table 2. Samples from the marginal phase (JH03, JH10 and JH11) of the Qingyang body are granodiorite with SiO2 ranging from 65.6 % to 68.5 % and K2O+Na2O from 7.09 % to 7.72 %. As noted above, JH03 is located close to the boundary between the marginal and inner phases, and JH10 furthest away from the boundary. Increase of SiO2 contents towards the centre is accompanied by decreases in FeO, MgO and CaO and is consistent with the marginal phase having solidified inwards with a significant differentiation of the magma. Compared with even the most evolved marginal phase sample (JH03), sample JH01 of the Qingyang body inner phase has higher SiO2 (72.1 %) and K2O+Na2O (8.06 %) contents combined with lower Fe2O3, MgO and CaO contents. Samples from the Jiuhuashan body have higher SiO2 (74.3–75.5 %) and K2O+Na2O (8.32–8.87 %) abundances and are alkali-feldspar granites.
XRF analyses of granitoids from the Jiuhuashan–Qingyang complex
The molar Al2O3/(CaO+Na2O+K2O) ratios are 0.94–0.98 for the marginal granodiorites, 1.01 for the inner monzogranite and 0.98–1.07 for the central alkali-feldspar granites. The molar (K2O+Na2O)/Al2O3 ratios are 0.64–0.81 for the marginal granodiorites, and 0.81 for the inner monzogranite. Alkali-feldspar granites of the Jiuhuashan body have molar (K2O+Na2O)/Al2O3 ratios higher than 0.94.
4.b. Trace element geochemistry
The trace element analyses for representative samples are presented in Table 3. ICP-MS results of both laser ablation on fused glass samples (LA) and solution samples (S) are reasonably consistent (see Fig. 4). The Eu concentrations in alkali-feldspar granites of the Jiuhuashan body are close to or below the detection limit of the LA-ICPMS analyses. Overall, the analytical data from solution samples are more precise with lower detection limits, but results obtained by both methods can be used for the following discussion.
Trace element compositions analysed by LA-ICPMS method (LA) and solution method (S)
b.d.–below detection limit.
Primitive mantle-normalized trace element diagram (a, c) and chondrite-normalized REE patterns (b, d) of the Jiuhuashan–Qingyang complex. The chondrite values and primitive mantle values are after Anders & Grevesse (Reference Anders and Grevesse1989) and McDonough & Sun (Reference McDonough and Sun1995), respectively. Grey area: Late Yanshanian calc-alkaline granites in the coastal area of SE China (25 analyses from Li & Zhou, Reference Li and Zhou2000; Xie et al. Reference Xie, Xu, Xing and Zou2003; Geng et al. Reference Geng, Xu, O'Reilly, Zhao and Sun2006). Hatched area: Late Yanshanian granites in the NE Yangtze Block (17 analyses from Yuan et al. Reference Yuan, Zhou, Yue, Zhu and Hou2003).
The Qingyang granodiorite and monzogranite samples have Rb/Sr ratios < 1, with Rb between 93–154 ppm and Sr between 189–617 ppm. The Zr/Hf ratios vary little (27.7–36.9). The Jiuhuashan granites have much higher Rb/Sr ratios (> 30), with very high Rb (> 343 ppm) and very low Sr (< 11.2 ppm) contents. The Zr/Hf ratios of Jiuhuashan granites are consistently lower (13.8–24.4) than those of the Qingyang granodiorite and monzogranite. The Ce/Pb and Nb/U ratios of Qingyang granodiorite and monzogranite are also different from those of the Jiuhuashan granites.
On the primitive mantle normalization spider diagram (Fig. 4a, c), the Qingyang granodiorite and monzogranite display similar patterns that are characterized by consistent enrichment toward the larger ionic elements. Jiuhuashan alkali-feldspar granites are similar to each other, and are characterized by enrichment in Rb, Th, U, Nb, Ta and Hf, and depletion in Ba, Sr, Nd, Sm, Eu, Gd and Ti, which are obviously different from patterns for Qingyang granodiorite and monzogranite. The chondrite-normalized REE patterns are shown on the right side in Figure 4b and d. The patterns also show significant differences between the Qingyang and Jiuhuashan granitic samples. The Qingyang granodiorite and monzogranite samples show consistent enrichment in La with flat heavy rare earth element patterns, while Jiuhuashan alkali-feldspar granites show a V-shaped pattern with a strong Eu negative anomaly. The (La/Yb)N ratios of the Jiuhuashan alkali-feldspar granites (4.5–7.3) are distinctly lower than those (12.7–35.6) of the Qingyang granodiorite and monzogranite.
Precise trace element (including large ion lithophile element) analysis for the granites in the Yangzte fold belt, NE Yangtze Block, has not been reported. The available rare earth element data for the other granites in this region are incorporated in Figure 4b and d. Apparently, the chondrite-normalized REE patterns of the Qingyang granodiorite and monzogranite are similar to those of other granites in the same region, while the Jiuhuashan granites show a distinct Eu negative anomaly. The trace element data from contemporary calc-alkaline granites in the coastal area of SE China are also collected and displayed in Figure 4 for comparison, and their petrogenetic implications will be discussed below.
4.c. Zircon U–Pb dating
Except for a few inherited zircons (age data in Table A1, available online as supplementary material at http://multimediafluids.uam.elogim.com/journals/geo; see discussion below), zircon crystals from the Qingyang granodiorite and monzogranite are euhedral with oscillatory zoning. Zircons from the Jiuhuashan alkali-feldspar granites are also euhedral and oscillatory zoned but many are sector zoned. Backscattered electron images (BSE) of representative zircon grains are shown in Figure 5. Because of errors in counting statistics during the analysis, 207Pb/206Pb ages are more precise for older (> 1 Ga) zircons, while 206Pb/238U ages are more precise for younger zircons (Griffin et al. Reference Griffin, Belousova, Shee, Pearson and O'Reilly2004). Therefore, we use the 207Pb/206Pb ages for older (> 1 Ga) zircons and 206Pb/238U ages for younger zircons (Table A1) in the following discussion. Concordia plots and weighted averages (Figs 6, 7) were constructed using Isoplot 2.49 (Ludwig, Reference Ludwig2001).
Backscattered electron images of representative zircons.
Zircon U–Pb concordia diagram for four samples from the Jiuhuashan–Qingyang complex.
Weighted average 206Pb–238U ages for four samples from the Jiuhuashan-Qingyang complex.
Most of the zircons separated from two rock samples (JH03 and JH04) of the marginal phase are concordant (Fig. 6b, c); main populations of the two samples both give ages of about 140 Ma, but two grains (JH03–01 and JH04–12, Table A1), interpreted as inherited, give ages of 165 Ma and 237 Ma, respectively. In addition, two grains from sample JH03 give younger 206Pb/238U ages of 93 Ma and 108 Ma, respectively, which may represent the age of metasomatism (see discussion below). The main populations for the two rock samples yield weighted mean 206Pb/238U ages of 140.0 ± 1.1 Ma (n = 14, MSWD = 0.64) and 139.7 ± 0.9 Ma (n = 19, MSWD = 0.77), respectively. Except for one zircon grain (JH01–10, Table A1) which is Archaean (2557 Ma), all other zircons separated from the inner phase of the Qingyang body plot on or near concordia (Fig. 6a). The weighted mean age of 19 zircons is 133.2 ± 1.3 Ma (MSWD = 1.5, Fig. 7), significantly younger than the marginal phase.
Zircons separated from a single rock sample (JH07) of the Jiuhuashan body show two distinct age groups on the concordia plot (Fig. 6d), but most are disconcordant. The weighted mean 206Pb/238U age of one group is 127.5 ± 1.6 Ma (MSWD = 0.47), while that of the other group is 100.8 ± 1.3 Ma (MSWD = 2.8, Fig. 7).
4.d. CHIME monazite and zircon dating
Monazite and zircon in JH08 alkali-feldspar granite were dated by the CHIME method (for analytical data see Appendix Table A2, available online at http://multimediafluids.uam.elogim.com/journals/geo). Monazites form subhedral grains 0.1–0.2 mm in length, and occur mostly in quartz or along grain boundaries between main constituents. A total of 63 spots were analysed. The ThO2 content ranges from 1.26 to 11.9 wt %, the UO2 content from 0.02 to 0.47 wt % and the Y2O3 content from 0.10 to 0.83 wt %. Many analyses show high concentration of K, and the (Ca+Si)/(Th+U+Pb+S) ratio deviated from unity; these are used as criteria for discordance (Suzuki & Kato, Reference Suzuki and Kato2008). Possibly concordant analyses, therefore, were screened by the criteria K2O < 0.015 wt % (close to the detection limits at 2 sigma) and 0.95 < (Ca+Si)/(Th+U+Pb+S) < 1.05. The screened monazites form two different trends on the diagram: data points on the upper trend (solid circles, > 110 Ma in apparent age) define an isochron of 127.6 ± 5.3 Ma, and those on the lower trend (open squares) yield an isochron of 96.1 ± 6.3 Ma (Fig. 8a). The spots showing younger ages tend to be located on marginal parts of the analysed grain. Zircon analyses were screened with chemical criteria: CaO < 0.015 and K2O < 0.015 (Suzuki & Kato, Reference Suzuki and Kato2008). The screened 22 analyses (of 50) were classified into two groups. Isochron analyses with apparent ages older than 110 Ma give 129.1 ± 10.1 Ma and the rest give 90.8 ± 9.9 Ma (Fig. 8b). Although showing a much larger possible age range, the CHIME monazite and zircon ages agree well with the LA-ICPMS zircon ages of 127.5 ± 1.6 and 100.8 ± 1.3 Ma.
CHIME plots of (a) monazite and (b) zircon from JH08 alkali-feldspar granite in the Jiuhuashan body. ThO2* shows the sum of the measured ThO2 and ThO2 equivalent to the measured UO2, and UO2* shows the sum of the measured UO2 and UO2 equivalent to the measured ThO2.
5. Discussion
The above dating results clearly show that the marginal granodiorite of the Qingyang body was crystallized at 140 Ma, and the inner monzogranite of the Qingyang body was crystallized at 133 Ma. Inherited zircons in granodiorite and monzogranite suggest involvement of both Mesozoic (237 Ma and 165 Ma) and Neoarchaean (2557 Ma) materials in magmas of the Qingyang body. The implications of dating results for the Jiuhuashan alkali-feldspar granite body need to be further discussed, including petrographical input.
Petrographical observations show that Jiuhuashan alkali-feldspar granite experienced a metasomatic event that developed albite veins on K-feldspar and formed the microperthite. The replacement starts from the mineral margin, and sometimes almost all microperthites are replaced by albite, therefore the metasomatic agent should be sodium-rich. Although zircons are known to be stable in various geological environments and are suitable for U–Th–Pb age dating, several studies showed the disruption of the isotopic system at temperatures below 900 °C in the presence of fluids (e.g. Rizvanova et al. Reference Rizvanova, Levchenkov, Belous, Bezmen, Maslenikov, Komarov, Makeev and Levskiy2000; Cherniak & Watson, Reference Cherniak and Watson2000; Geisler et al. Reference Geisler, Pidgeon, Kurtz, van Bronswijk and Schleicher2003a,Reference Geisler, Ulonska, Schleicher, Pidgeon and van Bronswijkb; Martin et al. Reference Martin, Duchêne, Deloule and Vanderhaeghe2006). Metamict (radiation-damaged) grains or portions of a single grain can easily recrystallize under hydrothermal conditions (Geisler et al. Reference Geisler, Ulonska, Schleicher, Pidgeon and van Bronswijk2001); hydrothermal zircons can be formed during sodic metasomatism (albitization) (Pelleter et al. Reference Pelleter, Cheilletz, Gasquet, Mouttaqi, Annich, Hakour, Deloule and Feraud2007) and may be used for hydrothermal event dating (Geisler et al. Reference Geisler, Rashwan, Rahn, Poller, Zwingmann, Pidgeon, Schleicher and Tomashek2003b; Pelleter et al. Reference Pelleter, Cheilletz, Gasquet, Mouttaqi, Annich, Hakour, Deloule and Feraud2007). However, hydrothermal zircon is an ‘imprecise term’ that refers to all zircons crystallized from, or altered by, an aqueous fluid (Hoskin, Reference Hoskin2005) and is difficult to distinguish from magmatic zircon.
The present dating disclosed two different ages for crystallization and metasomatism for the Jiuhuashan alkali-feldspar granites. Because of the metasomatism, some of the zircons were recrystallized, especially those at the rim of microperthite and showing disconcordance on the concordia plot (Fig. 6). We believe that the age of 127 Ma represents the crystallization age, and the age of 100 Ma may date the metasomatic event. This explanation is supported by published 40Ar–39Ar dates that gave an age of 122.7 ± 1.2 Ma for the Jiuhuashan alkali-feldspar granite (Chen, Zhou & Foland, Reference Chen, Zhou and Foland1985; Chen, Foland & Zhou, Reference Chen, Foland, Zhou and Wu1985; Chen et al. Reference Chen, Zhou, Li, Foland, Huang and Lu1993). The two age groups of zircons have distinct differences in U and Th abundance, that is, the older (magmatic) zircons have low U (< 1558 ppm) and Th (< 2860 ppm), and U+Th < 4418 ppm, while the younger (hydrothermal) zircons have high U (> 3197 ppm) and Th (> 4321 ppm), and U+Th > 7518 ppm. The metasomatic event also partly reset the zircon ages in the Qingyang body, that is, the zircons with younger resetting ages (c. 100 Ma) have also been identified in the Qingyang granite (JH03–02 and JH03–06 in Table A1 and Fig. 6). Therefore, the c. 100 Ma ages of zircon and monazite likely represent the time of the metasomatic alteration in the Jiuhuashan complex.
Chen, Foland & Zhou (Reference Chen, Foland, Zhou and Wu1985) and Chen et al. (Reference Chen, Zhou, Li, Foland, Huang and Lu1993) analysed the Sr–Nd and oxygen isotopes of the Jiuhuashan complex. Both Qingyang granodiorite and Jiuhuashan granite have similar initial 87Sr/86Sr and 143Nd/144Nd ratios of about 0.7085 and 0.51220, respectively. Overall, whole-rock δ18O values range from 7.0 to 9.9 ‰, and therefore minor isotopic heterogeneities are apparent. The high Sr initial ratios, low Nd initial ratios and high δ18O values indicate the dominance of old crust in the formation of these granitoid magmas. Chen, Foland & Zhou (Reference Chen, Foland, Zhou and Wu1985) and Chen et al. (Reference Chen, Zhou, Li, Foland, Huang and Lu1993) argued that the magmas were produced by crustal anatexis and that no mantle melts were involved directly in the production of the granitoids. They further postulated Proterozoic ages for source rocks (Proterozoic Shangxi Group) on the basis of the Nd model ages of 1000 to 1170 Ma. However, field geological investigations show there is a swarm of mafic enclaves in the Qingyang body. The presence of typical chilled margins on some enclaves is evidence of a syn-plutonic intrusion of basaltic magma, and therefore the previous interpretation for Sr and Nd isotopic compositions should be revisited. Firstly, if the isotopic characteristics of the magmas are very similar to those of the Proterozoic metamorphic rocks (Shangxi Group), then they should have older Nd model ages (> 1400 Ma) (Chen & Jahn, Reference Chen and Jahn1998). Secondly, the contemporary Yaocun granite (132 Ma) in the same region was generated apparently with juvenile input, which should be mantle-derived magma; the dark enclaves were formed by incomplete mixing of intermediate–basic magma with granitic magma (Ling, Zhai & Zhang, Reference Ling, Zhai and Zhang1990). Thirdly, nearby contemporary mafic rocks (e.g. gabbro in 30 km north with an age of 137 Ma: Wu et al. Reference Wu, Zhou, Huang, Zhang and Huang1996) show enriched Sr–Nd isotopic characteristics, with initial 87Sr/86Sr ranging from 0.7056 to 0.7071 and 143Nd/144Nd ratios of about 0.51214 to 0.51234, indicating an origin from enriched lithospheric mantle (Yan, Chen & Xu, Reference Yan, Chen and Xu2008). In fact, normal geothermal gradients are seldom sufficient to provide the necessary heat for partial melting of the crust. Crustal doubling, by thrusting or homogeneous thickening, likewise fails to provide sufficient heat. The extra heat required might be provided through mantle upwelling and crustal thinning, and possibly through the intra- and underplating of mafic magmas (Clemens, Reference Clemens2003 and references therein). The dark, microgranular igneous-textured enclaves occurring in the Qingyang body may represent globules of quenched, more mafic magma mingled with the host granitic magma. Therefore, although the Jiuhuashan–Qingyang complex shows S-type granite affinity, it is likely that limited mantle-derived magma was involved directly in the production of the granitoids.
The younger Nd model ages (c. 1000 to 1170 Ma) of the granitoid magmas could have resulted from anatexis of old crust (Nd model ages > 1800 Ma, and with Neoarchaean relics) mixed with limited juvenile material. Compared with the suggested ratios of OIB (Ce/Pb ≈ 25 ± 5; Nb/U ≈ 47 ± 10), primitive mantle (Ce/Pb ≈ 9 and Nb/U ≈ 30) and continental crust (Ce/Pb ≈ 4 and Nb/U ≈ 10) (Hofmann et al. Reference Hofmann, Jochum, Seufert and White1986), the Ce/Pb and Nb/U ratios of the Qingyang granodiorite and monzogranite, and that of the Jiuhuashan alkali-feldspar granites imply that they are basically derived by crustal melting. The Ce/Pb ratio of the Qingyang granodiorite could be as high as 5.98 (Table 3), however, which may again imply the mixing of limited juvenile material during the magma generation.
The very different trace element abundances of the Qingyang and Jiuhuashan bodies could be due to either the difference in source rock composition or the difference in degree of fractionation. The close similarity in initial Sr and Nd isotopic ratios seems to favour the second option.
As the whole-rock Sr and Eu are hosted mainly in plagioclase, and the Ba, Ti, Fe and Mg are hosted mainly in biotite, the depletion of these elements in the Jiuhuashan body may reflect the separation of plagioclase and biotite. Depletion in whole-rock Ca stabilizes monazite instead of allanite in alkali-feldspar granite of the Jiuhuashan body. Evidently, monazite behaves as a major repository of lighter rare earth elements. Alkali-feldspar granites in the Jiuhuashan body contain substantial amounts of thorite, while the mode of zircon remains unchanged. Thorite incorporates heavy rare earth elements, giving a convex-upward chondrite-normalized REE pattern with a maximum around Dy (Suzuki, Adachi & Yamamoto, Reference Suzuki, Adachi and Yamamoto1990). The high content of Nb in alkali-feldspar granites is due to the presence of minute amounts of fergusonite. This mineral shows a strong presence of heavy rare earth elements; the Yb and Lu contents could be as high as 4 and 0.5 wt %, respectively (Suzuki, Adachi & Yamamoto, Reference Suzuki, Adachi and Yamamoto1990). The combined effect of the plagioclase, monazite, thorite and fergsonite REE patterns accounts for the V-shaped normalized REE pattern of highly evolved Jiuhuashan alkali-feldspar granites.
The dating results coupled with the geochemical studies suggest that the Jiuhuashan–Qingyang complex formed by initial ballooning of the Qingyang body and subsequent upwelling of the mobile Jiuhuashan body, similarly to the Bergell pluton in the border of Switzerland and Italy (Pitcher, Reference Pitcher1997). In the first stage, a large volume of magma rose as a balloon to the level of neutral buoyancy and solidified gradually, from the marginal part at c. 140 Ma to the inner part at c. 133 Ma, with magmatic differentiation. This ballooning was possibly triggered by the intrusion/underplating of basaltic magma, as indicated by numerous enclaves with chilled margins. In the second stage, because of the extensional tectonic setting (Yan et al. Reference Yan, Liu, Song, Xu, An, Liu and Dai2009), highly evolved magma of the Jiuhuashan body was pushed aside by the pre-emplaced Qingyang body, and crystallized at 127 Ma. In the third stage (c. 100 Ma), parts of the alkali-feldspar granite changed into albite granite because of metasomatic infiltration of Na-rich fluid that was probably liberated from crystallizing syenite dykes.
Therefore, the present study provides ages which are consistent with the previous dating results (Chen, Zhou & Foland, Reference Chen, Zhou and Foland1985; Chen, Foland & Zhou, Reference Chen, Foland, Zhou and Wu1985) obtained by different methods. This work also provides additional constraints on the genesis, source materials, emplacement mechanism and metasomatic overprint of the Jiuhuashan–Qingyang complex.
The isotopic age histogram of Mesozoic granite-volcanic rocks of SE China shows that there was about a 25 Ma magmatically inactive period during Early Jurassic times (205–180 Ma). This tectonic quiescence is regarded as the tectonic regime change from the influence of the Indosinian orogeny as part of the large-scale Tethyan tectonics to the influence of the Yanshanian orogeny genetically associated with the western Pacific tectonics (Zhou et al. Reference Zhou, Sun, Shen, Shu and Niu2006). Therefore, SE China became an active continental margin from Jurassic to Cretaceous time (Zhou & Li, Reference Zhou and Li2000; Zhou et al. Reference Zhou, Sun, Shen, Shu and Niu2006), and the margin was related to the subduction of the palaeo-Pacific plate. The Late Mesozoic granitoid-volcanic rocks were the products of the NW–WNW subduction of the palaeo-Pacific plate beneath the eastern Asian continent. In detail, the Late Mesozoic magmatism in the SE China underwent three stages (Zhou et al. Reference Zhou, Sun, Shen, Shu and Niu2006): (1) intraplate magmatism including initial rift-type magmatism at the Early Yanshanian stage (Middle to Late Jurassic period), (2) continental margin arc magmatism at the early Late Yanshanian stage (Early Cretaceous), and (3) tholeiitic basalt volcanism recorded in red beds of back-arc basins at the Late Yanshanian stage (Late Cretaceous).
Although agreeing that Cretaceous magmatism in eastern China was mainly controlled by the subduction of the Pacific plate, Sun et al. (Reference Sun, Ding, Hu and Li2007) argued that the Cretaceous geological evolution matches well with the drifting history of the Pacific plate, and proposed that the major tectonic change from extension to transpression in eastern China occurred contemporaneously with an abrupt change of ~ 80° in the drifting direction of the subducting Pacific plate, that is, the drifting direction of the Pacific plate has changed several times since 140 Ma. The first major event occurred at 125–122 Ma, when the drifting direction changed from roughly southward to northwestward.
We tend to favour the idea that granites in Yangtze foldbelt (NE Yangtze Block) were controlled by the northwestward subduction of the Pacific plate, because (1) the Yangtze foldbelt is NE-striking tectonically; (2) most of the granite bodies in this region are enlongated in a NE–SW orientation, which is consistent with the distribution of regional Late Yanshanian granites in the coastal area.
Preliminary comparisons of trace element (including large ion lithophile element) analyses for the Late Yanshanian granites in the Yangzte fold belt and in the coastal area of SE China (Fig. 4) show that their spider diagram and chondrite-normalized REE patterns are similar, except for the evolved Jiuhuashan granites. Xu et al. (Reference Xu, Dong, Li and Zhou1999) and Zhou et al. (Reference Zhou, Sun, Shen, Shu and Niu2006) recognized that the extension-induced deep crustal melting and the underplating of basaltic magmas were the two main driving forces for the Yanshanian granitic magmatism in the coastal area of SE China. As discussed above, the Late Yanshanian granites in the Yangzte fold belt were produced in the same tectonic setting as the granites in the coastal area. Their Sr–Nd isotope compositions are also similar, with initial Sr isotope ratios (0.7058–0.7104) and epsilon Nd values (−5 to −7) (Chen et al. Reference Chen, Zhou, Li, Foland, Huang and Lu1993) for the Late Yanshanian granites in the Jiangnan zone of the Yangzte fold belt, and similar to the initial Sr isotope ratios (average 0.71012) and epsilon Nd values (average −6.97) for all of the Late Yanshanian granites in SE China (Shen, Ling & Sun, Reference Shen, Ling, Sun and Zhou2007). However, they were developed on different crustal basement (Fig. 1), and the granites in the NE Yangtze Block were basically derived by crustal melting with limited mixing of juvenile material during magma generation.
6. Conclusions
The Jiuhuashan–Qingyang complex in southern Anhui is subdivided into the main Qingyang body and the central Jiuhuashan body. Integrating petrographical, petrochemical and geochronological data, we draw the following conclusions:
(1) The Qingyang body of the complex was formed during the Cretaceous period, its marginal phase was crystallized at 140 Ma, and the inner phase was crystallized at c. 133 Ma. Neoarchaean restitic zircon was detected in this study, which suggests the involvement of old lower crust materials during the magmatism. In conjunction with petrographical studies, both LA-ICPMS zircon U–Pb ages and the CHIME monazite and zircon ages show that the Jiuhuashan body was crystallized at 127 Ma, and experienced metasomatism at c. 100 Ma.
(2) The enrichment of Rb, Th, U, Nb, Ta and Hf, depletion of Ba, Sr, Nd, Sm, Eu, Gd and Ti on the spider diagram, and the V-shaped normalized REE pattern of the Jiuhuashan alkali-feldspar granites are ascribable to the separation of plagioclase and biotite, and crystallization of thorite and fergusonite.
(3) The Jiuhuashan–Qingyang complex, together with other granites in the NE Yangtze Block, was derived by crustal anatexis but with limited mixing of juvenile material during the magma generation, which was triggered by the northwestward subduction of the Pacific plate.
Acknowledgements
We thank He ZY for help with zircon U–Pb dating, Dr Richard Flood, two anonymous reviewers and editor Professor David Pyle for their very helpful comments. This research was financially supported by the National Natural Science Foundation of China (grant no. 40730313), National Major Basic Research Project of China (2006CB403508) and research grant (2008-I-02) from the State Key Laboratory for Mineral Deposits Research, Nanjing University.
