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Self-similar breakup of polymeric threads as described by the Oldroyd-B model

Published online by Cambridge University Press:  28 January 2020

J. Eggers*
Affiliation:
School of Mathematics, University of Bristol, Fry Building, Bristol BS8 1UG, UK
M. A. Herrada
Affiliation:
E.S.I., Universidad de Sevilla, Camino de los Descubrimientos s/n 41092, Spain
J. H. Snoeijer
Affiliation:
Physics of Fluids Group, Faculty of Science and Technology, Mesa+ Institute, University of Twente, 7500 AE Enschede, The Netherlands
*
†Email address for correspondence: Jens.Eggers@bristol.ac.uk

Abstract

When a drop of fluid containing long, flexible polymers breaks up, it forms threads of almost constant thickness, whose size decreases exponentially in time. Using an Oldroyd-B fluid as a model, we show that the thread profile, rescaled by the thread thickness, converges to a similarity solution. Using the correspondence between viscoelastic fluids and nonlinear elasticity, we derive similarity equations for the full three-dimensional axisymmetric flow field in the limit that the viscosity of the solvent fluid can be neglected. Deriving a conservation law along the thread, we can calculate the stress inside the thread from a measurement of the thread thickness. The explicit form of the velocity and stress fields can be deduced from a solution of the similarity equations. Results are validated by detailed comparison with numerical simulations.

Information

Type
JFM Papers
Copyright
© The Author(s), 2020. Published by Cambridge University Press
Figure 0

Figure 1. An illustration of the problem studied in this paper. In (a), a sequence of experimental images showing the pinch-off of a drop of polymer solution (polyacrylamide) between two solid plates, forming a uniform thread of radius $h_{thr}(t)$ (Deblais, Velikov & Bonn 2018b). In (b,c), our numerical simulation of the Oldroyd-B model for flexible polymer solutions, with dimensionless parameters (defined in § 2.3), chosen as in Turkoz et al. (2018): $De=60$, $Oh=3.16$, $S=\unicode[STIX]{x1D702}_{s}/\unicode[STIX]{x1D702}_{0}=0.25$. The elasto-capillary number is $E_{c}=\unicode[STIX]{x1D702}_{p}R_{0}/(\unicode[STIX]{x1D706}\unicode[STIX]{x1D6FE})=0.0395$. Times are made dimensionless with the capillary time scale $\unicode[STIX]{x1D70F}$, and lengths are given in units of the initial bridge radius $R_{0}$. In (b), $h_{thr}(t)$ is shown to decrease exponentially in time, with decay exponent $1/3\unicode[STIX]{x1D706}$, where $\unicode[STIX]{x1D706}$ is the polymer time scale (blue line). For comparison, we also include a simulation with infinite relaxation time, keeping $E_{c}$ constant. In (c), a close up of the corner region between the thread and the drop, showing the axial stress $\unicode[STIX]{x1D70E}_{zz}$. The stress is very high inside the thread, and decays very rapidly in the transition region.

Figure 1

Figure 2. Results of a numerical simulation with parameters as in figure 1, rescaled to similarity variables according to (3.6). The profiles for three different times collapse onto a time-independent similarity solution. Panels (a–d) are the components of the stress tensor, evaluated at the surface, while (e–h) show the components of the velocity, the pressure (again at the surface), as well as the surface profile itself. All profiles collapse onto the time-independent similarity solution defined by (3.6). The profiles (as well as all corresponding results below) have been interpolated with splines as appropriate for their representation as fourth-order polynomials inside our numerical code.

Figure 2

Figure 3. Contour plots of stresses, rescaled according to (3.6), obtained as in figure 2, for the last dimensionless time $t/\unicode[STIX]{x1D70F}=550$.

Figure 3

Figure 4. The axial stress $\overline{\unicode[STIX]{x1D70E}}_{zz}$ on the surface (a), and a magnified view of the thread radius $\overline{h}$ (b), as a function of $\overline{z}$, for the last dimensionless time $t/\unicode[STIX]{x1D70F}=550$. At $\overline{z}=5$, inside the drop, the stress has decayed by five orders of magnitude relative to its value inside the thread. The thread radius, shown on the right, only varies by a relative amount of 10-5 over its entire length.

Figure 4

Figure 5. A convergence study of the axial stress distribution inside the uniform thread, taken at the middle of the thread $z=0$. Panels (a,c,e) correspond to $S=\unicode[STIX]{x1D702}_{s}/\unicode[STIX]{x1D702}_{0}=0.25$ as in figure 1, and (b,d,f) to $S=0.7$; all other parameters are as in figure 1. Panels (a,b) demonstrate convergence toward a self-similar stress distribution, which remains non-constant over the radius, as the dimensionless exit velocity converges toward its asymptotic value (c,d). Panels (e,f) show the self-similar stress profiles $\overline{\unicode[STIX]{x1D70E}}_{0}(\overline{r})$. The shape of the profiles, scaled according to (3.6), depends on the solvent ratio $S$.

Figure 5

Figure 6. Convergence of the elastic solution toward the similarity solution (4.16) for smaller and smaller values of the dimensionless elasto-capillary number $E_{c}=GR_{0}/\unicode[STIX]{x1D6FE}$. Stresses have been rescaled according to (4.25). Profiles from the similarity solution as described in § 4.4 are shown as the dashed line for comparison.

Figure 6

Figure 7. The transformation $Z_{0}(\unicode[STIX]{x1D709})$ designed to account for stretching in the $Z$-direction for three values of $E_{c}$.

Figure 7

Figure 8. The interface $\overline{h}(\overline{z})$ in similarity variables. The solid line is the rescaled profile obtained from the simulation for $E_{c}=10^{-6}$, the dashed line is the solution to the similarity equations. The thread thickness is $\overline{h}_{0}$; for large arguments the profile grows exponentially.

Figure 8

Figure 9. Convergence onto the similarity solution. In (a), the ratio $\overline{h}_{\overline{z}}/\overline{h}$ approaches the limit $a=2^{4/3}/3$, over a wide range of $\overline{Z}$. In (b), we show contours of the function $\unicode[STIX]{x1D6F1}$ in the $[\unicode[STIX]{x1D719},\unicode[STIX]{x1D713}]$ domain, showing the transition region between the thread and the drop region. Red dashed lines correspond to contours obtained by rescaling the pressure in the elastic simulation with $E_{c}=10^{-6}$. Although the radial dependence is weak, the profile is not one-dimensional.

Figure 9

Figure 10. Comparison of the similarity solution as described in § 4.4 with the rescaled profiles (3.6) obtained from the time-dependent simulation shown in figure 1 for $De=60$. The time-dependent simulation has been rescaled according to (3.6), with an effective $R_{0}$ chosen such that $\overline{\unicode[STIX]{x1D70E}}_{zz}=2^{4/3}$ inside the thread.