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Role of soluble surfactant in linear stability of a liquid film flowing down a compliant substrate

Published online by Cambridge University Press:  13 May 2025

Arghya Samanta*
Affiliation:
Department of Applied Mechanics, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110016, India
*
Corresponding author: Arghya Samanta, arghya@am.iitd.ac.in

Abstract

A linear stability analysis of a soluble surfactant-laden liquid film flowing down a compliant substrate is performed. Our purpose is to expand the prior studies (Carpenter and Garrad 1985 J. Fluid Mech. 155, 465–510; Alexander et al., 2020 J. Fluid Mech. 900, A40) by incorporating a soluble surfactant into the flow configuration. As a result, we formulate the Orr–Sommerfeld-type boundary value problem and solve it analytically by using the long-wave series expansion as well as numerically by using the Chebyshev spectral collocation method in an arbitrary wavenumber regime for infinitesimal disturbances. The long-wave result reveals that surface instability is stabilized in the presence of a surfactant, whereas it is destabilized in the presence of a compliant substrate. These opposing impacts suggest an analytical relationship between parameters associated with the soluble surfactant and compliant wall, ensuring the same critical Reynolds number for the emergence of surface instability corresponding to both surfactant-laden film flow over a compliant wall and surfactant-free film flow over a non-compliant wall. In the arbitrary wavenumber regime, along with the surface mode, we identify two additional modes based on their distinct phase speeds. Specifically, the wall mode emerges in the finite wavenumber regime, while the shear mode emerges only when the Reynolds number is large. As the surfactant Marangoni number increases, the wall mode destabilizes, resulting in a different outcome from the surface mode. Moreover, increasing the value of the ratio of adsorption and desorption rate constants stabilizes surface instability but destabilizes wall mode instability. As a result, we perceive that the soluble surfactant-laden film flow is linearly more unstable than the insoluble one due to surface instability but linearly more stable than the insoluble one due to wall mode instability. Additionally, we see a peculiar behaviour of base surface surfactant concentration on the primary instability. In fact, it has a specific value depending on adsorption and desorption rate constants below which surface instability stabilizes but wall mode instability destabilizes, whereas above which an opposite phenomenon occurs. Finally, in the high-Reynolds-number regime, we can suppress shear mode instability by raising the surfactant Marangoni number and the ratio of adsorption and desorption rate constants when the angle of inclination is sufficiently small. Unlike surface instability, the base surface surfactant concentration exhibits both stabilizing and destabilizing influences on shear mode instability.

Information

Type
JFM Papers
Copyright
© The Author(s), 2025. Published by Cambridge University Press
Figure 0

Figure 1. Sketch of a two-dimensional viscous liquid film flowing down a compliant substrate, where the liquid film is contaminated by a soluble surfactant. Here $U(y)$ represents the base velocity for the undisturbed parallel film flow, $h(x,t)$ represents the height of the disturbed film flow and $\eta (x,t)$ represents the location of the deformed compliant substrate from the $x$ axis.

Figure 1

Figure 2. Sketch of an impermeable compliant substrate, where $b$ is the thickness of the compliant substrate that is supported by an array of springs. We assume that a surfactant-free inviscid liquid occupies the cavity between the elastic plate and the rigid substrate.

Figure 2

Figure 3. (a) Variation of the critical Reynolds number for the onset of surface instability as the parameter $\xi _s$ changes when $C_K=5$. Solid, dashed, dotted and dash-dotted lines stand for $\xi _s=10^3$, $\xi _s=10^2$, $\xi _s=10^1$ and $\xi _s=10^0$, respectively. The circle and cross symbols are the results of Samanta (2021a) and Alexander et al. (2020), respectively. (b) Variation of the critical Reynolds number for the onset of surface instability as the parameter $C_K$ changes when $\xi _s=10^3$. Solid, dashed and dotted lines stand for $C_K=5$, $C_K=10$ and $C_K=100$, respectively. The circle symbols are the results of Wei (2005). The triangle symbol represents the maximum value of the critical Reynolds number on each curve. Thin dashed lines in figures 3(a) and 3(b) represent for the maximum value of the critical Reynolds number for varying $\xi _s$ and $C_K$, respectively. The other parameters are $Ma_s=1$ and $\theta =45^{\circ }$.

Figure 3

Figure 4. Variation of the critical Reynolds number for the onset of surface instability as the parameter $\xi _s$ changes when $Ma_s=1$, $\theta =45^{\circ }$ and $\Gamma _E=0.1$. Solid, dashed and dotted lines stand for $\xi _s=10^3$, $\xi _s=10^0$ and $\xi _s=10^{-1}$, respectively. The circle and star symbols are the results of Samanta (2021a) and Alexander et al. (2020), respectively. The solid red points represent the range of $Re$ for a linearly stable flow.

Figure 4

Table 1. Analytical and numerical values of the critical Reynolds number for the threshold of surface instability when $\xi _s$ alters. The other parameters are $C_I=C_D=C_B=C_T=1$, $C_K=5$, $Ca=Pe_b=Pe_s=Ma_s=k_s=1$, $\Gamma _E=0.1$ and $\theta =45^{\circ }$.

Figure 5

Figure 5. (a) Variation of the neutral stability curve for the surface mode in the ($Re$, $k$) plane for different values of $C_K$ when $C_D=1$ and $Ca=0.001$. Solid, dashed, dotted and dash-dotted lines stand for $C_K=5$, $C_K=3$, $C_K=2.6$ and $C_K=2$, respectively. The different symbols are the results of Alexander et al. (2020). (b) Variation of the neutral stability curve for the wall mode in the ($Re$, $k$) plane for different values of $C_K$ when $C_D=0.32$ and $Ca=1$. Solid, dashed and dotted lines stand for $C_K=10$, $C_K=7.5$ and $C_K=5$, respectively. The different symbols are the results of Samanta (2021a). The other parameters are $C_I=C_B=C_T=1$, $Ma_s=0$, $Pe_b=Pe_s=k_s=1$, $\Gamma _E=0.1$, $\xi _s=10^3$ and $\theta =45^{\circ }$. Here $U$ and $S$ represent unstable and stable regions.

Figure 6

Figure 6. Spectrum of the eigenvalue problem (4.11) in the ($c_r$, $c_i$) plane when $Re=4$, $C_D=0.32$, $C_K=5$ and $\theta =45^{\circ }$. The red circle symbols represent the results at $k=0.5$. The black dots show the shifting of unstable modes from their previous locations when $k \in (0,\ 0.5)$. The other parameters are $C_I=C_B=C_T=1$, $Ca=1$, $Ma_s=0$, $Pe_b=Pe_s=k_s=1$, $\Gamma _E=0.1$ and $\xi _s=10^3$.

Figure 7

Figure 7. (a) Variation of the neutral stability curve for the surface mode in the ($Re$, $k$) plane for different values of $Ma_s$. (b) Variation of the temporal growth rate $kc_i$ with wavenumber $k$ for the surface mode when $Re=2$. Solid, dashed, dotted and dash-dotted lines stand for $Ma_s=0$, $Ma_s=1$, $Ma_s=2$ and $Ma_s=4$, respectively. The other parameters are $C_I=C_B=C_T=1$, $C_K=5$, $C_D=0.32$, $Ca=1$, $Pe_b=Pe_s=k_s=1$, $\Gamma _E=0.1$, $\xi _s=10^3$ and $\theta =45^{\circ }$. Here $U$ and $S$ represent unstable and stable regions.

Figure 8

Figure 8. (a) Variation of the neutral stability curve for the wall mode in the ($Re$, $k$) plane for different values of $Ma_s$. (b) Variation of the temporal growth rate $kc_i$ with wavenumber $k$ for the wall mode when $Re=2$. Solid, dashed, dotted and dash-dotted lines stand for $Ma_s=0$, $Ma_s=1$, $Ma_s=2$ and $Ma_s=4$, respectively. (c) Comparison between the temporal growth rates corresponding to the surface mode and the wall mode when $Re=2$. Thick and thin lines represent results for the surface mode and the wall mode, respectively. The other parameters are $C_I=C_B=C_T=1$, $C_K=5$, $C_D=0.32$, $Ca=1$, $Pe_b=Pe_s=k_s=1$, $\Gamma _E=0.1$, $\xi _s=10^3$ and $\theta =45^{\circ }$. Here $U$ and $S$ represent unstable and stable regions.

Figure 9

Figure 9. (a) Variation of the neutral stability curves for both the surface mode and wall mode in the ($Re$, $k$) plane for different values of $Ma_s$. Solid, dashed and dotted lines stand for $Ma_s=0$, $Ma_s=4$ and $Ma_s=8$, respectively. (b) Variation of the neutral stability curves for both the surface mode and the wall mode in the ($Re$, $k$) plane when $Ma_s \approx 4.873$. The other parameters are $C_I=C_B=C_T=1$, $C_K=5$, $C_D=0.38$, $Ca=1$, $Pe_b=Pe_s=k_s=1$, $\Gamma _E=0.1$, $\xi _s=10^3$ and $\theta =45^{\circ }$. The star symbols represent the critical Reynolds numbers for the surface mode and the wall mode, respectively. Here $U$ and $S$ represent unstable and stable regions. Thick and thin lines represent results for the surface mode and the wall mode, respectively.

Figure 10

Figure 10. (a) Variation of the neutral stability curve for the surface mode in the ($Re$, $k$) plane for different values of $\xi _s$. (b) Variation of the temporal growth rate $kc_i$ with wavenumber $k$ for the surface mode when $Re=2$. Solid, dashed, dotted and dash-dotted lines stand for $\xi _s=10^3$, $\xi _s=10^1$, $\xi _s=10^0$ and $\xi _s=10^{-1}$, respectively. The other parameters are $C_I=C_B=C_T=1$, $C_K=5$, $C_D=0.32$, $Ca=1$, $Ma_s=2$, $Pe_b=Pe_s=k_s=1$, $\Gamma _E=0.1$ and $\theta =45^{\circ }$. Here $U$ and $S$ represent unstable and stable regions. The circle and diamond symbols are the results of Samanta (2021a) and Alexander et al. (2020), respectively.

Figure 11

Figure 11. (a) Variation of the neutral stability curve for the wall mode in the ($Re$, $k$) plane for different values of $\xi _s$. (b) Variation of the temporal growth rate $kc_i$ with wavenumber $k$ for the wall mode when $Re=0.6$. (c) Comparison between the temporal growth rates corresponding to the surface mode and the wall mode when $Re=2$. Thick and thin lines represent results for the surface mode and the wall mode, respectively. Solid, dashed, dotted and dash-dotted lines stand for $\xi _s=10^3$, $\xi _s=10^1$, $\xi _s=10^0$ and $\xi _s=10^{-1}$, respectively. The other parameters are $C_I=C_B=C_T=1$, $C_K=5$, $C_D=0.32$, $Ca=1$, $Ma_s=2$, $Pe_b=Pe_s=k_s=1$, $\Gamma _E=0.1$ and $\theta =45^{\circ }$. Here $U$ and $S$ represent unstable and stable regions. The circle and diamond symbols are the results of Samanta (2021a) and Alexander et al. (2020), respectively.

Figure 12

Figure 12. (a) Variation of the neutral stability curves for both the surface mode and the wall mode in the ($Re$, $k$) plane for different values of $\Gamma _E$ (${\lt } 0.55$). Solid, dashed and dotted lines stand for $\Gamma _E=0.1$, $\Gamma _E=0.3$ and $\Gamma _E=0.5$, respectively. (b) Variation of the neutral stability curves for both the surface mode and the wall mode in the ($Re$, $k$) plane for different values of $\Gamma _E$ (${\gt } 0.55$). Solid, dashed and dotted lines stand for $\Gamma _E=0.6$, $\Gamma _E=0.7$ and $\Gamma _E=0.8$, respectively. The other parameters are $C_I=C_B=C_T=1$, $C_K=5$, $C_D=0.38$, $Ca=1$, $Ma_s=1$, $Pe_b=Pe_s=k_s=1$, $\xi _s=10^1$ and $\theta =45^{\circ }$. Here $U$ and $S$ represent unstable and stable regions. Thick and thin lines represent results for the surface mode and the wall mode, respectively.

Figure 13

Figure 13. (a) Variation of the neutral stability curves for both the surface mode and the wall mode in the ($Re$, $k$) plane for different values of $Pe_b$ when $Pe_s=1$. Solid and dashed lines stand for $Pe_b=10^0$ and $Pe_b=10^3$, respectively. (b) Variation of the neutral stability curves for both the surface mode and the wall mode in the ($Re$, $k$) plane for different values of $Pe_s$ when $Pe_b=1$. Solid, dashed and dotted lines stand for $Pe_s=10^0$, $Pe_s=10^2$ and $Pe_s=10^3$, respectively. The other parameters are $C_I=C_B=C_T=1$, $C_K=5$, $C_D=0.38$, $Ca=1$, $Ma_s=2$, $k_s=1$, $\xi _s=10^3$, $\Gamma _E=0.1$ and $\theta =45^{\circ }$. Here $U$ and $S$ represent unstable and stable regions. Thick and thin lines represent results for the surface mode and the wall mode, respectively.

Figure 14

Figure 14. Spectrum of the eigenvalue problem (4.11) when $Re=10^5$, $C_D=10$, $C_K=10^5$ and $\theta =4^{\circ }$. (a) The red circle symbols represent the results at $k=0.5$. The black dots show the shifting of modes from their previous locations when $k \in (0.1,\ 0.5)$. (b) The red circle symbols represent the results at $k=3$. The black dots show the shifting of modes from their previous locations when $k \in (2,\ 3)$. The other parameters are $C_I=C_B=C_T=1$, $Ca=1$, $Ma_s=0$, $Pe_b=Pe_s=k_s=1$, $\Gamma _E=0.1$ and $\xi _s=10^3$. The inset figures show a zoom in of the surface mode, wall mode and shear mode.

Figure 15

Figure 15. (a) Variation of the normalized eigenfunction for the shear mode in the $y$ direction when $k=0.5$. (b) Contour plot of the streamfunction in the ($x$, $y$) plane for the shear mode when $k=0.5$. (c) Variation of the normalized eigenfunction for the surface mode in the $y$ direction when $k=0.5$. (d) Contour plot of the stream function in ($x$, $y$) plane for the surface mode when $k=0.5$. (e) Variation of the normalized eigenfunction for the wall mode in the $y$ direction when $k=3$. (f) Contour plot of the streamfunction in the ($x$, $y$) plane for the wall mode when $k=3$. (g) Variation of the normalized eigenfunction for the surface mode in the $y$ direction when $k=3$. (h) Contour plot of the streamfunction in the ($x$, $y$) plane for the surface mode when $k=3$. The other parameters are $Re=10^5$, $C_D=10$, $C_K=10^5$, $\theta =4^{\circ }$, $C_I=C_B=C_T=1$, $Ca=1$, $Ma_s=0$, $Pe_b=Pe_s=k_s=1$, $\Gamma _E=0.1$ and $\xi _s=10^3$. Solid and dotted lines represent the real and imaginary parts of $\psi$, respectively.

Figure 16

Figure 16. (a) Variation of the neutral stability curves for both the shear mode and the wall mode in the ($Re$, $k$) plane for different values of $Ma_s$. (b) Variation of the temporal growth rate $kc_i$ with wavenumber $k$ for the shear mode when $Re=10^4$. Solid, dashed and dotted lines stand for $Ma_s=0$, $Ma_s=40$ and $Ma_s=80$, respectively. The other parameters are $C_I=C_B=C_T=1$, $C_K=10^5$, $C_D=10$, $Ca=1$, $Pe_b=Pe_s=k_s=1$, $\Gamma _E=0.1$, $\xi _s=10^3$ and $\theta =4^{\circ }$. Here $U$ and $S$ represent unstable and stable regions. Thick and thin lines represent results for the shear mode and the wall mode, respectively. The circle symbols are the results of Alexander et al. (2020).

Figure 17

Figure 17. (a) Variation of the neutral stability curve for the shear mode in the ($Re$, $k$) plane for different values of $Ma_s$. (b) Variation of the temporal growth rate $kc_i$ with wavenumber $k$ for the shear mode when $Re=7000$. Solid, dashed and dotted lines stand for $Ma_s=0$, $Ma_s=40$ and $Ma_s=80$, respectively. The other parameters are $C_I=C_B=C_T=1$, $C_K=10^4$, $C_D=10$, $Ca=1$, $Pe_b=Pe_s=k_s=1$, $\Gamma _E=0.1$, $\xi _s=10^3$ and $\theta =1^{\prime }=1^{\circ }/60$. Here $U$ and $S$ represent unstable and stable regions.

Figure 18

Figure 18. (a) Variation of the neutral stability curve for the shear mode in the ($Re$, $k$) plane for different values of $\xi _s$. (b) Variation of the temporal growth rate $kc_i$ with wavenumber $k$ for the shear mode when $Re=7000$. Solid, dashed and dotted lines stand for $\xi _s=10^3$, $\xi _s=10^1$ and $\xi _s=10^{-1}$, respectively. The other parameters are $C_I=C_B=C_T=1$, $C_K=10^4$, $C_D=10$, $Ca=1$, $Ma_s=100$, $Pe_b=Pe_s=k_s=1$, $\Gamma _E=0.1$ and $\theta =1^{\prime }=1^{\circ }/60$. Here $U$ and $S$ represent unstable and stable regions. The circle symbols are the results of Samanta (2021a).

Figure 19

Figure 19. (a) Variation of the neutral stability curve for the shear mode in the ($Re$, $k$) plane for different values of $\Gamma _E$. Solid, dashed and dotted lines stand for $\Gamma _E=0.1$, $\Gamma _E=0.2$ and $\Gamma _E=0.3$, respectively. (b) Variation of the neutral stability curve for the shear mode in the ($Re$, $k$) plane for different values of $\Gamma _E$. Solid, dashed and dotted lines stand for $\Gamma _E=0.7$, $\Gamma _E=0.8$ and $\Gamma _E=0.9$, respectively. The other parameters are $C_I=C_B=C_T=1$, $C_K=10^4$, $C_D=10$, $Ca=1$, $Ma_s=100$, $Pe_b=Pe_s=k_s=1$, $\xi _s=10^1$ and $\theta =1^{\prime }=1^{\circ }/60$. Here $U$ and $S$ represent unstable and stable regions.