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Ovonic threshold switching selectors for three-dimensional stackable phase-change memory

Published online by Cambridge University Press:  05 September 2019

Min Zhu
Affiliation:
Shanghai Institute of Microsystem and Information Technology, China; minzhu@mail.sim.ac.cn
Kun Ren
Affiliation:
Shanghai Institute of Microsystem and Information Technology, and Hangzhou Dianzi University, China; kun.ren.nick@outlook.com
Zhitang Song
Affiliation:
Shanghai Institute of Microsystem and Information Technology, China; ztsong@mail.sim.ac.cn

Abstract

High-current switching performance of ovonic threshold switching (OTS) selectors have successfully enabled the commercialization of high-density three-dimensional (3D) stackable phase-change memory in Intel’s 3D Xpoint technology. This bridges the huge performance gap between dynamic random access memory (DRAM) and Flash. Similar to phase-change memory, OTS uses chalcogenide-based materials, but whereas phase-change memory reversibly switches between a high-resistance amorphous phase and a low-resistance crystalline phase, OTS freezes in the amorphous phase. In this article, we review recent developments in OTS materials and their performance in devices, especially current density and selectivity. Advantages and challenges of OTS devices in the integration with the phase-change memory are discussed. We introduce the evolution of theoretical models for explaining the OTS behavior, including thermal runaway, field-induced nucleation, and generation/recombination of charge carriers.

Information

Type
Phase-Change Materials in Electronics and Photonics
Copyright
Copyright © Materials Research Society 2019 
Figure 0

Figure 1. (a) Performance gap in the storage architecture of a current computer. (b) Photo of 3D Xpoint memory released by Intel in 2015. (c) 1S1R stackable crossbar structure of 3D Xpoint memory, showing a selected memory cell in the high-resistance state (1). (d) Ovonic threshold switch (OTS) + phase-change memory (PCM) in a 3D stackable crosspoint array reported by Intel in 2009. The inset highlights one integrated memory cell consisting of one OTS and one PCM cell. (e) Voltage–current curve of a PCM device, showing ovonic memory switching behavior. (f) Voltage–current curve of an OTS device, distinct from that of PCM. Note: S, selector; M, phase-change memory; CPU, central processing unit; SRAM, static random–access memory; DRAM, dynamic random–access memory.

Figure 1

Figure 2. The evolution of emerging ovonic threshold switching (OTS) materials since 2009.11,12,23,30–52 The red star highlights the breakthrough achievement of a 3D stackable crossbar phase-change memory array with OTS elements by Intel in 2009; the OTS material used is still unknown.

Figure 2

Table I. Summary of ovonic threshold switching device performances using different materials.23,32–52

Figure 3

Figure 3. Scalability of current densities with device size provided by GeAsTeSiN-based ovonic threshold switching (OTS)32 and current densities required for operating GeSbTe-based phase-change memory.53

Figure 4

Figure 4. Three representative models to explain the ovonic threshold switching (OTS) phenomena: (a) thermal runaway,54,55 (b) field-induced nucleation,57,58 and (c) pure electrical phenomenon (yellow bars represent metal electrode).66 Note: RE,0, critical size of nuclei induced by electric field; R0, critical size of nuclei induced by thermal energy; Ev, valence band; Ec, conduction band.