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5 - One-Dimensional Potential Steps, Barriers, and Wells

Published online by Cambridge University Press:  27 December 2025

Ana María Cetto
Affiliation:
Universidad Nacional Autónoma de México, Mexico
Luis de la Peña
Affiliation:
Universidad Nacional Autónoma de México, Mexico
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Summary

Chapter 5 familiarizes the student with some of the most basic features of quantum systems, by applying the Schrödinger equation to simple, one-dimensional problems. It shows that it is possible to obtain qualitatively correct conclusions about the behavior of quantum particles in the presence of more or less arbitrary potentials by replacing them with piecewise-constant potentials, which greatly simplifies the mathematics. Replacing the real potential with a simpler one that retains its basic characteristics has the great advantage of allowing us to study the essence of the physical situation, as illustrated by the examples of the one-dimensional potential step, the square well, the square potential barrier and the symmetric double well. These examples are used to discuss specific features such as quantum tunneling, and applications such as masers and molecular clocks.

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