High-power rectification at X-band remains challenging because the diode must simultaneously offer a sufficiently high cutoff frequency and sustain large RF voltages. This work presents a 5.6-W, 10-GHz high-efficiency practical Class-F harmonic-terminated rectifier developed through device–circuit co-design. A custom finger-type GaN Schottky diode is fabricated, achieving a low zero-bias capacitance of
$0.19\,\text{pF}$, a breakdown voltage of
$205\,\text{V}$, a turn-on voltage of
$1.24\,\text{V}$, and a series resistance of
$11\,\Omega$, corresponding to a cutoff frequency of
$76\,\text{GHz}$. These characteristics enable fast switching and low parasitic losses suitable for high-power microwave rectification, and device reliability is confirmed through stable operation at
$350\,\text{K}$ and a 24-h stress test. Leveraging this diode, the rectifier is optimized with a harmonic-termination network to realize the intended Class-F boundary conditions through controlled second- and third-harmonic impedances. Measurements show a peak RF-to-DC efficiency of
$62.1\%$ at an input power of
$37.5\,\text{dBm}$ with a
$470\,\Omega$ load. Rather than pursuing a single absolute performance metric, the core contribution lies in demonstrating a device–circuit co-design methodology. By integrating targeted device optimization with harmonic-termination circuit design, this approach addresses combined challenges of frequency and power scaling in high-power X-band microwave rectification.